DOI: 10.1063/1.446480. Picosecond study of an intermediate in the <i>trans</i> to <i>cis</i> isomerization pathway of stiff stilbene [Penn]

Picosecond study of an intermediate in the trans to cis isomerization pathway of stiff stilbene

10.1063/1.446480

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A picosecond spectroscopic study of trans 1,1′-biindanylidene (‘‘stiff’’ stilbene) has exposed a transient absorption at 351 nm which is not an electronically excited state of the trans or cis forms. The signal strength increases with decreasing viscosity in a manner that is consistent with the decay of the excited trans molecules being the precursor of the new transient. The data suggest that after the viscosity dependent formation of the intermediate, it decays with a time constant of 10±3 ps into cis stiff stilbene. It is suggested that the intermediate is the ‘‘phantom’’ state of stilbene photochemistry.

Bibliography

Doany, F. E., Heilweil, E. J., Moore, R., & Hochstrasser, R. M. (1984). Picosecond study of an intermediate in the trans to cis isomerization pathway of stiff stilbene. The Journal of Chemical Physics, 80(1), 201â206.

Authors 4

F. E. Doany (first)
E. J. Heilweil (additional)
R. Moore (additional)
R. M. Hochstrasser (additional)

References 30 Referenced 64

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Dates

Type	When
Created	22 years, 6 months ago (Feb. 28, 2003, 12:18 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 8:48 p.m.)
Indexed	1 year, 3 months ago (May 8, 2024, 6:39 a.m.)
Issued	41 years, 7 months ago (Jan. 1, 1984)
Published	41 years, 7 months ago (Jan. 1, 1984)
Published Print	41 years, 7 months ago (Jan. 1, 1984)

Funders 0

None

BibTeX

@article{Doany_1984, title={Picosecond study of an intermediate in the trans to cis isomerization pathway of stiff stilbene}, volume={80}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.446480}, DOI={10.1063/1.446480}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Doany, F. E. and Heilweil, E. J. and Moore, R. and Hochstrasser, R. M.}, year={1984}, month=jan, pages={201–206} }

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