DOI: 10.1063/1.446332. The relation between the changes of thermodynamic quantities at the glass transition and the long-wavelength fluctuations of glass structure

The relation between the changes of thermodynamic quantities at the glass transition and the long-wavelength fluctuations of glass structure

10.1063/1.446332

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The thermodynamic relation between the discontinuity of the longitudinal elastic compliance at the glass transition and the long-wavelength density fluctuations in the glass is rederived using the formal framework of linear response theory. Analogous new relations are derived for the discontinuities of the specific heat and the thermal expansion coefficient. From these relations a new interpretation of the Prigogine–Defay ratio in terms of the correlation between enthalpy and volume fluctuations is obtained.

Authors 1

Josef Jäckle (first)

References 24 Referenced 21

10.1021/cr60135a002 / Chem. Rev. (1948)
10.1080/00018735300101252 / Adv. Phys. (1953)
10.1111/j.1749-6632.1976.tb39693.x / Ann. N. Y. Acad. Sci. (1976)
{'key': '2024021000131504900_r4'}
10.1063/1.1734202 / J. Chem. Phys. (1963)
10.1063/1.432063 / J. Chem. Phys. (1976)
10.1080/01418638108224037 / Philos. Mag. B (1981)
10.1111/j.1151-2916.1973.tb12398.x / J. Am. Ceram. Soc. (1973)
10.1007/BFb0117367 / Prog. Colloid Polym. Sci. (1979)
10.1063/1.1654141 / Appl. Phys. Lett. (1972)
10.1016/0022-3093(75)90113-1 / J. Non-Cryst. Solids (1975)
10.1016/0003-4916(63)90078-2 / Ann. Phys. (N.Y.) (1963)
10.1016/0030-4018(73)90230-7 / Opt. Commun. (1973)
{'key': '2024021000131504900_r13'}
10.1103/PhysRevA.9.1740 / Phys. Rev. A (1974)
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10.1080/00268978000100461 / Mol. Phys. (1980)
10.1107/S0021889872009227 / J. Appl. Cryst. (1972)
10.1016/0031-9163(63)90055-6 / Phys. Lett. (1963)
10.1063/1.1663555 / J. Appl. Phys. (1974)
10.1016/0022-3093(79)90035-8 / J. Non-Cryst. Solids (1979)
{'key': '2024021000131504900_r21'}
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{'key': '2024021000131504900_r23'}

Dates

Type	When
Created	22 years, 6 months ago (Feb. 28, 2003, 12:03 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 8:37 p.m.)
Indexed	20 hours, 55 minutes ago (Sept. 4, 2025, 9:46 a.m.)
Issued	41 years, 10 months ago (Nov. 1, 1983)
Published	41 years, 10 months ago (Nov. 1, 1983)
Published Print	41 years, 10 months ago (Nov. 1, 1983)

Funders 0

None

BibTeX

@article{J_ckle_1983, title={The relation between the changes of thermodynamic quantities at the glass transition and the long-wavelength fluctuations of glass structure}, volume={79}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.446332}, DOI={10.1063/1.446332}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Jäckle, Josef}, year={1983}, month=nov, pages={4463–4467} }

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