DOI: 10.1063/1.445550. Energy transfer in surface enhanced luminescence

Energy transfer in surface enhanced luminescence

10.1063/1.445550

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Radiationless energy transfer from excited dye molecules to silver islands has been studied. The dye is separated from the metal surface by a thin layer of SiOx. When the spacer layer thickness is increased from d=0, an increase in the luminescence intensity is observed. For the low quantum yield dye Basic Fuchsin, a maximum luminescence enhancement of 200 is observed at dSiO≂25 Å, relative to dye on an inert substrate. With further increase in spacer thickness, the luminescence intensity drops rapidly toward the unenhanced value. The results are interpreted in terms of competition between local field enhancement and loss of excitation by energy transfer to the metal.

Bibliography

Wokaun, A., Lutz, H.-P., King, A. P., Wild, U. P., & Ernst, R. R. (1983). Energy transfer in surface enhanced luminescence. The Journal of Chemical Physics, 79(1), 509â514.

Authors 5

A. Wokaun (first)
H.-P. Lutz (additional)
A. P. King (additional)
U. P. Wild (additional)
R. R. Ernst (additional)

References 44 Referenced 227

10.1063/1.442161 / J. Chem. Phys. (1981)
{'key': '2024020923380497000_r2', 'first-page': '1170', 'volume': '44', 'year': '1980', 'journal-title': 'Phys. Rev. Lett.'} / Phys. Rev. Lett. (1980)
10.1016/0009-2614(80)80356-3 / Chem. Phys. Lett. (1980)
10.1103/PhysRevLett.45.1519 / Phys. Rev. Lett. (1980)
{'key': '2024020923380497000_r4', 'first-page': '1291', 'volume': '76', 'year': '1982', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1982)
{'key': '2024020923380497000_r5'}
10.1016/0009-2614(81)85095-6 / Chem. Phys. Lett. (1981)
10.1016/0375-9601(80)90726-4 / Phys. Lett. A (1980)
10.1039/f29797500790 / J. Chem. Soc. Faraday Trans. (1979)
10.1016/0009-2614(80)80647-6 / Chem. Phys. Lett. (1980)
10.1016/0009-2614(81)85172-X / Chem. Phys. Lett. (1981)
10.1103/PhysRevLett.46.145 / Phys. Rev. Lett. (1981)
{'key': '2024020923380497000_r12', 'first-page': '849', 'volume': '24', 'year': '1981', 'journal-title': 'Phys. Rev. B'} / Phys. Rev. B (1981)
{'key': '2024020923380497000_r13'}
10.1364/OL.5.000368 / Opt. Lett. (1980)
10.1364/OL.6.000245 / Opt. Lett. (1981)
10.1103/PhysRevB.24.4906 / Phys. Rev. B (1981)
10.1063/1.445486 / J. Chem. Phys. (1983)
10.1063/1.441699 / J. Chem. Phys. (1981)
10.1063/1.442333 / J. Chem. Phys. (1981)
{'key': '2024020923380497000_r19', 'first-page': '1', 'volume': '37', 'year': '1978', 'journal-title': 'Adv. Chem. Phys.'} / Adv. Chem. Phys. (1978)
10.1063/1.443938 / J. Chem. Phys. (1982)
{'key': '2024020923380497000_r21', 'first-page': '1179', 'volume': '70', 'year': '1966', 'journal-title': 'Ber. Bunsenges. Phys. Chem.'} / Ber. Bunsenges. Phys. Chem. (1966)
{'key': '2024020923380497000_r21a'}
10.1016/0009-2614(80)85113-X / Chem. Phys. Lett. (1980)
10.1016/0009-2614(80)80692-0 / Chem. Phys. Lett. (1980)
10.1063/1.442683 / J. Chem. Phys. (1982)
10.1364/OL.6.000251 / Opt. Lett. (1981)
10.1364/OL.7.000089 / Opt. Lett. (1982)
10.1016/0022-2313(81)90226-X / J. Lumin. (1981)
{'key': '2024020923380497000_r26'}
{'key': '2024020923380497000_r27'}
10.1016/0039-6028(69)90196-4 / Surf. Sci. (1969)
10.1021/ja01517a023 / J. Am. Chem. Soc. (1959)
{'key': '2024020923380497000_r29'}
10.1021/ja01223a055 / J. Am. Chem. Soc. (1945)
{'key': '2024020923380497000_r31', 'first-page': '507', 'volume': '11', 'year': '1973', 'journal-title': 'Indian J. Pure Appl. Phys.'} / Indian J. Pure Appl. Phys. (1973)
10.1016/0039-6028(78)90263-7 / Surf. Sci. (1978)
10.1063/1.440560 / J. Chem. Phys. (1980)
10.1103/PhysRevB.6.4370 / Phys. Rev. B (1972)
10.1016/0040-6090(73)90221-6 / Thin Solid Films (1973)
10.1016/0040-6090(74)90099-6 / Thin Solid Films (1974)
10.1364/JOSA.64.001563 / J. Opt. Soc. Am. (1974)
10.1063/1.444243 / J. Chem. Phys. (1982)

Dates

Type	When
Created	22 years, 6 months ago (Feb. 28, 2003, 12:03 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 8:07 p.m.)
Indexed	2 months ago (July 2, 2025, 1:51 p.m.)
Issued	42 years, 2 months ago (July 1, 1983)
Published	42 years, 2 months ago (July 1, 1983)
Published Print	42 years, 2 months ago (July 1, 1983)

Funders 0

None

BibTeX

@article{Wokaun_1983, title={Energy transfer in surface enhanced luminescence}, volume={79}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.445550}, DOI={10.1063/1.445550}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Wokaun, A. and Lutz, H.-P. and King, A. P. and Wild, U. P. and Ernst, R. R.}, year={1983}, month=jul, pages={509–514} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        2
      ]
    ],
    "date-time": "2025-07-02T17:51:29Z",
    "timestamp": 1751478689995
  },
  "reference-count": 44,
  "publisher": "AIP Publishing",
  "issue": "1",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1983,
        7,
        1
      ]
    ]
  },
  "abstract": "<jats:p>Radiationless energy transfer from excited dye molecules to silver islands has been studied. The dye is separated from the metal surface by a thin layer of SiOx. When the spacer layer thickness is increased from d=0, an increase in the luminescence intensity is observed. For the low quantum yield dye Basic Fuchsin, a maximum luminescence enhancement of 200 is observed at dSiO\u224225 \u00c5, relative to dye on an inert substrate. With further increase in spacer thickness, the luminescence intensity drops rapidly toward the unenhanced value. The results are interpreted in terms of competition between local field enhancement and loss of excitation by energy transfer to the metal.</jats:p>",
  "DOI": "10.1063/1.445550",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2003,
        2,
        28
      ]
    ],
    "date-time": "2003-02-28T17:03:55Z",
    "timestamp": 1046451835000
  },
  "page": "509-514",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 227,
  "title": "Energy transfer in surface enhanced luminescence",
  "prefix": "10.1063",
  "volume": "79",
  "author": [
    {
      "given": "A.",
      "family": "Wokaun",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Physical Chemistry Laboratory, Swiss Federal Institute of Technology, CH 8092 Z\u00fcrich, Switzerland"
        }
      ]
    },
    {
      "given": "H.-P.",
      "family": "Lutz",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Physical Chemistry Laboratory, Swiss Federal Institute of Technology, CH 8092 Z\u00fcrich, Switzerland"
        }
      ]
    },
    {
      "given": "A. P.",
      "family": "King",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Physical Chemistry Laboratory, Swiss Federal Institute of Technology, CH 8092 Z\u00fcrich, Switzerland"
        }
      ]
    },
    {
      "given": "U. P.",
      "family": "Wild",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Physical Chemistry Laboratory, Swiss Federal Institute of Technology, CH 8092 Z\u00fcrich, Switzerland"
        }
      ]
    },
    {
      "given": "R. R.",
      "family": "Ernst",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Physical Chemistry Laboratory, Swiss Federal Institute of Technology, CH 8092 Z\u00fcrich, Switzerland"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020923380497000_r1",
      "doi-asserted-by": "crossref",
      "first-page": "1139",
      "DOI": "10.1063/1.442161",
      "volume": "75",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020923380497000_r2",
      "first-page": "1170",
      "volume": "44",
      "year": "1980",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020923380497000_r2a",
      "doi-asserted-by": "crossref",
      "first-page": "201",
      "DOI": "10.1016/0009-2614(80)80356-3",
      "volume": "73",
      "year": "1980",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020923380497000_r3",
      "doi-asserted-by": "crossref",
      "first-page": "1519",
      "DOI": "10.1103/PhysRevLett.45.1519",
      "volume": "45",
      "year": "1980",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020923380497000_r4",
      "first-page": "1291",
      "volume": "76",
      "year": "1982",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020923380497000_r5"
    },
    {
      "key": "2024020923380497000_r6",
      "doi-asserted-by": "crossref",
      "first-page": "5",
      "DOI": "10.1016/0009-2614(81)85095-6",
      "volume": "82",
      "year": "1981",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020923380497000_r7",
      "doi-asserted-by": "crossref",
      "first-page": "381",
      "DOI": "10.1016/0375-9601(80)90726-4",
      "volume": "77",
      "year": "1980",
      "journal-title": "Phys. Lett. A"
    },
    {
      "key": "2024020923380497000_r8",
      "doi-asserted-by": "crossref",
      "first-page": "790",
      "DOI": "10.1039/f29797500790",
      "volume": "75",
      "year": "1979",
      "journal-title": "J. Chem. Soc. Faraday Trans."
    },
    {
      "key": "2024020923380497000_r9",
      "doi-asserted-by": "crossref",
      "first-page": "460",
      "DOI": "10.1016/0009-2614(80)80647-6",
      "volume": "76",
      "year": "1980",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020923380497000_r10",
      "doi-asserted-by": "crossref",
      "first-page": "355",
      "DOI": "10.1016/0009-2614(81)85172-X",
      "volume": "82",
      "year": "1981",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020923380497000_r11",
      "doi-asserted-by": "crossref",
      "first-page": "145",
      "DOI": "10.1103/PhysRevLett.46.145",
      "volume": "46",
      "year": "1981",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020923380497000_r12",
      "first-page": "849",
      "volume": "24",
      "year": "1981",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024020923380497000_r13"
    },
    {
      "key": "2024020923380497000_r14",
      "doi-asserted-by": "crossref",
      "first-page": "368",
      "DOI": "10.1364/OL.5.000368",
      "volume": "5",
      "year": "1980",
      "journal-title": "Opt. Lett."
    },
    {
      "key": "2024020923380497000_r15",
      "doi-asserted-by": "crossref",
      "first-page": "245",
      "DOI": "10.1364/OL.6.000245",
      "volume": "6",
      "year": "1981",
      "journal-title": "Opt. Lett."
    },
    {
      "key": "2024020923380497000_r16",
      "doi-asserted-by": "crossref",
      "first-page": "4906",
      "DOI": "10.1103/PhysRevB.24.4906",
      "volume": "24",
      "year": "1981",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024020923380497000_r17",
      "doi-asserted-by": "crossref",
      "first-page": "5324",
      "DOI": "10.1063/1.445486",
      "volume": "78",
      "year": "1983",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020923380497000_r18",
      "doi-asserted-by": "crossref",
      "first-page": "5321",
      "DOI": "10.1063/1.441699",
      "volume": "74",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020923380497000_r18a",
      "doi-asserted-by": "crossref",
      "first-page": "2205",
      "DOI": "10.1063/1.442333",
      "volume": "75",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020923380497000_r19",
      "first-page": "1",
      "volume": "37",
      "year": "1978",
      "journal-title": "Adv. Chem. Phys."
    },
    {
      "key": "2024020923380497000_r20",
      "doi-asserted-by": "crossref",
      "first-page": "1560",
      "DOI": "10.1063/1.443938",
      "volume": "77",
      "year": "1982",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020923380497000_r21",
      "first-page": "1179",
      "volume": "70",
      "year": "1966",
      "journal-title": "Ber. Bunsenges. Phys. Chem."
    },
    {
      "key": "2024020923380497000_r21a"
    },
    {
      "key": "2024020923380497000_r22",
      "doi-asserted-by": "crossref",
      "first-page": "499",
      "DOI": "10.1016/0009-2614(80)85113-X",
      "volume": "69",
      "year": "1980",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020923380497000_r23",
      "doi-asserted-by": "crossref",
      "first-page": "447",
      "DOI": "10.1016/0009-2614(80)80692-0",
      "volume": "73",
      "year": "1980",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020923380497000_r23a",
      "doi-asserted-by": "crossref",
      "first-page": "740",
      "DOI": "10.1063/1.442683",
      "volume": "76",
      "year": "1982",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020923380497000_r24",
      "doi-asserted-by": "crossref",
      "first-page": "251",
      "DOI": "10.1364/OL.6.000251",
      "volume": "6",
      "year": "1981",
      "journal-title": "Opt. Lett."
    },
    {
      "key": "2024020923380497000_r25",
      "doi-asserted-by": "crossref",
      "first-page": "89",
      "DOI": "10.1364/OL.7.000089",
      "volume": "7",
      "year": "1982",
      "journal-title": "Opt. Lett."
    },
    {
      "key": "2024020923380497000_r25a",
      "doi-asserted-by": "crossref",
      "first-page": "83",
      "DOI": "10.1016/0022-2313(81)90226-X",
      "volume": "24/25",
      "year": "1981",
      "journal-title": "J. Lumin."
    },
    {
      "key": "2024020923380497000_r26"
    },
    {
      "key": "2024020923380497000_r27"
    },
    {
      "key": "2024020923380497000_r27a",
      "doi-asserted-by": "crossref",
      "first-page": "349",
      "DOI": "10.1016/0039-6028(69)90196-4",
      "volume": "13",
      "year": "1969",
      "journal-title": "Surf. Sci."
    },
    {
      "key": "2024020923380497000_r28",
      "doi-asserted-by": "crossref",
      "first-page": "1869",
      "DOI": "10.1021/ja01517a023",
      "volume": "81",
      "year": "1959",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020923380497000_r29"
    },
    {
      "key": "2024020923380497000_r30",
      "doi-asserted-by": "crossref",
      "first-page": "1212",
      "DOI": "10.1021/ja01223a055",
      "volume": "67",
      "year": "1945",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020923380497000_r31",
      "first-page": "507",
      "volume": "11",
      "year": "1973",
      "journal-title": "Indian J. Pure Appl. Phys."
    },
    {
      "key": "2024020923380497000_r32",
      "doi-asserted-by": "crossref",
      "first-page": "L392",
      "DOI": "10.1016/0039-6028(78)90263-7",
      "volume": "75",
      "year": "1978",
      "journal-title": "Surf. Sci."
    },
    {
      "key": "2024020923380497000_r33",
      "doi-asserted-by": "crossref",
      "first-page": "3023",
      "DOI": "10.1063/1.440560",
      "volume": "73",
      "year": "1980",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020923380497000_r34",
      "doi-asserted-by": "crossref",
      "first-page": "4370",
      "DOI": "10.1103/PhysRevB.6.4370",
      "volume": "6",
      "year": "1972",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024020923380497000_r35",
      "doi-asserted-by": "crossref",
      "first-page": "63",
      "DOI": "10.1016/0040-6090(73)90221-6",
      "volume": "18",
      "year": "1973",
      "journal-title": "Thin Solid Films"
    },
    {
      "key": "2024020923380497000_r35a",
      "doi-asserted-by": "crossref",
      "first-page": "173",
      "DOI": "10.1016/0040-6090(74)90099-6",
      "volume": "21",
      "year": "1974",
      "journal-title": "Thin Solid Films"
    },
    {
      "key": "2024020923380497000_r35b",
      "doi-asserted-by": "crossref",
      "first-page": "1563",
      "DOI": "10.1364/JOSA.64.001563",
      "volume": "64",
      "year": "1974",
      "journal-title": "J. Opt. Soc. Am."
    },
    {
      "key": "2024020923380497000_r36",
      "doi-asserted-by": "crossref",
      "first-page": "3767",
      "DOI": "10.1063/1.444243",
      "volume": "77",
      "year": "1982",
      "journal-title": "J. Chem. Phys."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/79/1/509/18942801/509_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/79/1/509/18942801/509_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T01:07:08Z",
    "timestamp": 1707527228000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/79/1/509/217776/Energy-transfer-in-surface-enhanced-luminescence"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1983,
        7,
        1
      ]
    ]
  },
  "references-count": 44,
  "journal-issue": {
    "issue": "1",
    "published-print": {
      "date-parts": [
        [
          1983,
          7,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.445550",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1983,
        7,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1983,
        7,
        1
      ]
    ]
  }
}