DOI: 10.1063/1.445532. Kinetics of phase transitions: Theory of Ostwald ripening

Kinetics of phase transitions: Theory of Ostwald ripening

10.1063/1.445532

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A new derivation is presented for the last stage of phase separation in the kinetics of a first order phase transition, precipitation, where Ostwald ripening is the dominant mechanism. We use a time scaling technique and derive the power law time dependence and distribution function for the size of the particles of the new phase. Equations are derived for the correction terms to the distribution function and power laws. The derivation clarifies and corrects prior work.

Bibliography

Marqusee, J. A., & Ross, J. (1983). Kinetics of phase transitions: Theory of Ostwald ripening. The Journal of Chemical Physics, 79(1), 373â378.

Authors 2

J. A. Marqusee (first)
John Ross (additional)

References 14 Referenced 246

{'key': '2024020923433886100_r1'}
{'key': '2024020923433886100_r2'}
{'key': '2024020923433886100_r3'}
{'key': '2024020923433886100_r4'}
10.1016/0022-3697(61)90054-3 / Phys. Chem. Solids (1961)
{'key': '2024020923433886100_r6', 'first-page': '581', 'volume': '65', 'year': '1961', 'journal-title': 'Z. Elektrochem.'} / Z. Elektrochem. (1961)
10.1016/0022-3697(76)90046-9 / J. Phys. Chem. Solids (1976)
10.1007/BF00548725 / J. Mater. Sci. (1978)
10.1103/PhysRevB.15.4425 / Phys. Rev. B (1977)
10.1016/0001-8686(75)85001-9 / Adv. Colloid Interface Sci. (1975)
10.1039/dc9766100048 / Faraday Discuss. (1976)
10.1002/bbpc.19740781007 / Ber. Bunsenges Phys. Chem. (1974)
{'key': '2024020923433886100_r11', 'first-page': '343', 'volume': '35', 'year': '1976', 'journal-title': 'Adv. Phys.'} / Adv. Phys. (1976)
{'key': '2024020923433886100_r12'}

Dates

Type	When
Created	22 years, 5 months ago (Feb. 28, 2003, 12:03 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 8:11 p.m.)
Indexed	3 days, 8 hours ago (Aug. 20, 2025, 9:19 a.m.)
Issued	42 years, 1 month ago (July 1, 1983)
Published	42 years, 1 month ago (July 1, 1983)
Published Print	42 years, 1 month ago (July 1, 1983)

Funders 0

None

BibTeX

@article{Marqusee_1983, title={Kinetics of phase transitions: Theory of Ostwald ripening}, volume={79}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.445532}, DOI={10.1063/1.445532}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Marqusee, J. A. and Ross, John}, year={1983}, month=jul, pages={373–378} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        20
      ]
    ],
    "date-time": "2025-08-20T13:19:18Z",
    "timestamp": 1755695958516
  },
  "reference-count": 14,
  "publisher": "AIP Publishing",
  "issue": "1",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1983,
        7,
        1
      ]
    ]
  },
  "abstract": "<jats:p>A new derivation is presented for the last stage of phase separation in the kinetics of a first order phase transition, precipitation, where Ostwald ripening is the dominant mechanism. We use a time scaling technique and derive the power law time dependence and distribution function for the size of the particles of the new phase. Equations are derived for the correction terms to the distribution function and power laws. The derivation clarifies and corrects prior work.</jats:p>",
  "DOI": "10.1063/1.445532",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2003,
        2,
        28
      ]
    ],
    "date-time": "2003-02-28T17:03:55Z",
    "timestamp": 1046451835000
  },
  "page": "373-378",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 246,
  "title": "Kinetics of phase transitions: Theory of Ostwald ripening",
  "prefix": "10.1063",
  "volume": "79",
  "author": [
    {
      "given": "J. A.",
      "family": "Marqusee",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemistry, Stanford University, Stanford, California 94305"
        }
      ]
    },
    {
      "given": "John",
      "family": "Ross",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry, Stanford University, Stanford, California 94305"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020923433886100_r1"
    },
    {
      "key": "2024020923433886100_r2"
    },
    {
      "key": "2024020923433886100_r3"
    },
    {
      "key": "2024020923433886100_r4"
    },
    {
      "key": "2024020923433886100_r5",
      "doi-asserted-by": "crossref",
      "first-page": "35",
      "DOI": "10.1016/0022-3697(61)90054-3",
      "volume": "19",
      "year": "1961",
      "journal-title": "Phys. Chem. Solids"
    },
    {
      "key": "2024020923433886100_r6",
      "first-page": "581",
      "volume": "65",
      "year": "1961",
      "journal-title": "Z. Elektrochem."
    },
    {
      "key": "2024020923433886100_r7",
      "doi-asserted-by": "crossref",
      "first-page": "771",
      "DOI": "10.1016/0022-3697(76)90046-9",
      "volume": "37",
      "year": "1976",
      "journal-title": "J. Phys. Chem. Solids"
    },
    {
      "key": "2024020923433886100_r8",
      "doi-asserted-by": "crossref",
      "first-page": "1611",
      "DOI": "10.1007/BF00548725",
      "volume": "13",
      "year": "1978",
      "journal-title": "J. Mater. Sci."
    },
    {
      "key": "2024020923433886100_r9",
      "doi-asserted-by": "crossref",
      "first-page": "4425",
      "DOI": "10.1103/PhysRevB.15.4425",
      "volume": "15",
      "year": "1977",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024020923433886100_r10",
      "doi-asserted-by": "crossref",
      "first-page": "1",
      "DOI": "10.1016/0001-8686(75)85001-9",
      "volume": "5",
      "year": "1975",
      "journal-title": "Adv. Colloid Interface Sci."
    },
    {
      "key": "2024020923433886100_r10a",
      "doi-asserted-by": "crossref",
      "first-page": "48",
      "DOI": "10.1039/dc9766100048",
      "volume": "61",
      "year": "1976",
      "journal-title": "Faraday Discuss."
    },
    {
      "key": "2024020923433886100_r10b",
      "doi-asserted-by": "crossref",
      "first-page": "997",
      "DOI": "10.1002/bbpc.19740781007",
      "volume": "78",
      "year": "1974",
      "journal-title": "Ber. Bunsenges Phys. Chem."
    },
    {
      "key": "2024020923433886100_r11",
      "first-page": "343",
      "volume": "35",
      "year": "1976",
      "journal-title": "Adv. Phys."
    },
    {
      "key": "2024020923433886100_r12"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/79/1/373/18943213/373_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/79/1/373/18943213/373_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T01:11:59Z",
    "timestamp": 1707527519000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/79/1/373/217926/Kinetics-of-phase-transitions-Theory-of-Ostwald"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1983,
        7,
        1
      ]
    ]
  },
  "references-count": 14,
  "journal-issue": {
    "issue": "1",
    "published-print": {
      "date-parts": [
        [
          1983,
          7,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.445532",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1983,
        7,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1983,
        7,
        1
      ]
    ]
  }
}