DOI: 10.1063/1.445482. Theoretical study of the effects of vibrational-rotational interactions on the Raman spectrum of N2

Theoretical study of the effects of vibrational-rotational interactions on the Raman spectrum of N2

10.1063/1.445482

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A systematic study of the polarizability and polarizability derivatives of N2 is undertaken as a function of basis set and level of correlation treatment. The value obtained for the ratio of derivatives (re β′e/βe) of the polarizability anisotropy β=α∥−α⊥ is 3.15±0.2, which is larger than the two experimental estimates of 2.63±0.29 and 2.22±0.44.

Bibliography

Langhoff, S. R., Bauschlicher, C. W., & Chong, D. P. (1983). Theoretical study of the effects of vibrational-rotational interactions on the Raman spectrum of N2. The Journal of Chemical Physics, 78(9), 5287â5292.

Authors 3

Stephen R. Langhoff (first)
Charles W. Bauschlicher (additional)
Delano P. Chong (additional)

References 35 Referenced 65

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Dates

Type	When
Created	22 years, 6 months ago (Feb. 28, 2003, 11:47 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 5:47 p.m.)
Indexed	1 month, 4 weeks ago (July 2, 2025, 1:11 p.m.)
Issued	42 years, 4 months ago (May 1, 1983)
Published	42 years, 4 months ago (May 1, 1983)
Published Print	42 years, 4 months ago (May 1, 1983)

Funders 0

None

BibTeX

@article{Langhoff_1983, title={Theoretical study of the effects of vibrational-rotational interactions on the Raman spectrum of N2}, volume={78}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.445482}, DOI={10.1063/1.445482}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Langhoff, Stephen R. and Bauschlicher, Charles W. and Chong, Delano P.}, year={1983}, month=may, pages={5287–5292} }

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