Abstract
A systematic derivation, using the time-dependent formulation of Raman scattering, of some Placzek-type polarizability (PtP) tensors—the multidimensional reflection, the semiclassical coordinate space, and the locally linear coordinate-space polarizability tensors—which are dependent only on the nuclear coordinates are presented, and their limitations are discussed. Phase-space pictures are used to show the relationship between the various approximations from which the PtP tensors are derived. These PtP tensors are expected to be accurate, even on resonance, for repulsive, multidimensional excited state surfaces.
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Dates
Type | When |
---|---|
Created | 22 years, 6 months ago (Feb. 28, 2003, 11:47 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 9, 2024, 7:36 p.m.) |
Indexed | 2 months, 2 weeks ago (June 14, 2025, 12:15 a.m.) |
Issued | 42 years, 7 months ago (Jan. 15, 1983) |
Published | 42 years, 7 months ago (Jan. 15, 1983) |
Published Print | 42 years, 7 months ago (Jan. 15, 1983) |
@article{Lee_1983, title={Placzek-type polarizability tensors for Raman and resonance Raman scattering}, volume={78}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.444775}, DOI={10.1063/1.444775}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Lee, Soo-Y.}, year={1983}, month=jan, pages={723–734} }