DOI: 10.1063/1.444479. Ordered structure in dilute solutions of highly charged polymer lattices as studied by microscopy. I. Interparticle distance as a function of latex concentration

Ordered structure in dilute solutions of highly charged polymer lattices as studied by microscopy. I. Interparticle distance as a function of latex concentration

10.1063/1.444479

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The coexistence of ordered and disordered regions has been observed in dilute solutions of highly charged monodisperse latex particles, a copolymer of styrene and styrenesulfonate, by using a metallurgical microscope. Unlike latex particles of low charge numbers, the interparticle distances (2Dexp) in the hexagonal ordered regions are smaller than the calculated average values for a face-centered-cubic distribution (2D0,h) at low polymer concentrations (0.2–2 vol %). However, at high concentrations, up to 12%, the 2Dexp value approaches 2D0,h. The results are consistent with a ‘‘two-state structure’’ containing ordered and disordered regions and indicate the existence of ‘‘attractive’’ interactions between the charged solutes. The findings are also consistent with those for other species of high charge densities such as synthetic macroions and simple ions.

Bibliography

Ise, N., Okubo, T., Sugimura, M., Ito, K., & Nolte, H. J. (1983). Ordered structure in dilute solutions of highly charged polymer lattices as studied by microscopy. I. Interparticle distance as a function of latex concentration. The Journal of Chemical Physics, 78(1), 536â540.

Authors 5

N. Ise (first)
T. Okubo (additional)
M. Sugimura (additional)
K. Ito (additional)
H. J. Nolte (additional)

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Dates

Type	When
Created	22 years, 5 months ago (Feb. 28, 2003, 11:47 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 7:29 p.m.)
Indexed	4 months, 2 weeks ago (April 5, 2025, 5:07 a.m.)
Issued	42 years, 7 months ago (Jan. 1, 1983)
Published	42 years, 7 months ago (Jan. 1, 1983)
Published Print	42 years, 7 months ago (Jan. 1, 1983)

Funders 0

None

BibTeX

@article{Ise_1983, title={Ordered structure in dilute solutions of highly charged polymer lattices as studied by microscopy. I. Interparticle distance as a function of latex concentration}, volume={78}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.444479}, DOI={10.1063/1.444479}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Ise, N. and Okubo, T. and Sugimura, M. and Ito, K. and Nolte, H. J.}, year={1983}, month=jan, pages={536–540} }

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