DOI: 10.1063/1.444083. Matrix isolation studies of the reactions of silicon atoms. II. Infrared spectrum and structure of matrix-isolated fluorosilylene: HSiF

Matrix isolation studies of the reactions of silicon atoms. II. Infrared spectrum and structure of matrix-isolated fluorosilylene: HSiF

10.1063/1.444083

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Silicon spontaneously reacts with HF and DF to form the molecules HSiF and DSiF in solid argon. Photolysis of the matrix during deposition greatly enhances the yield of these products. Frequencies for the three infrared active modes of HSiF and DSiF have been accurately measured. The force field of this triatomic molecule has been fully determined through normal coordinate analyses. Thermodynamic functions for the fluorosilylene have been calculated.

Bibliography

Ismail, Z. K., Fredin, L., Hauge, R. H., & Margrave, J. L. (1982). Matrix isolation studies of the reactions of silicon atoms. II. Infrared spectrum and structure of matrix-isolated fluorosilylene: HSiF. The Journal of Chemical Physics, 77(4), 1626â1631.

Authors 4

Zakya Kafafi Ismail (first)
Leif Fredin (additional)
Robert H. Hauge (additional)
John L. Margrave (additional)

References 10 Referenced 34

10.1139/p64-038 / Can. J. Phys. (1964)
10.1139/p64-039 / Can. J. Phys. (1964)
10.1139/p72-072 / Can. J. Phys. (1972)
10.1139/p66-127 / Can. J. Phys. (1966)
10.1139/p66-047 / Can. J. Phys. (1966)
10.1021/ic50130a046 / Inorg. Chem. (1973)
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Dates

Type	When
Created	22 years, 6 months ago (Feb. 28, 2003, 11:32 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 7:15 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 7:33 p.m.)
Issued	43 years ago (Aug. 15, 1982)
Published	43 years ago (Aug. 15, 1982)
Published Print	43 years ago (Aug. 15, 1982)

Funders 0

None

BibTeX

@article{Ismail_1982, title={Matrix isolation studies of the reactions of silicon atoms. II. Infrared spectrum and structure of matrix-isolated fluorosilylene: HSiF}, volume={77}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.444083}, DOI={10.1063/1.444083}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Ismail, Zakya Kafafi and Fredin, Leif and Hauge, Robert H. and Margrave, John L.}, year={1982}, month=aug, pages={1626–1631} }

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