DOI: 10.1063/1.443518. Depolarized Raman scattering in normal and supercooled antimony trichloride

Depolarized Raman scattering in normal and supercooled antimony trichloride

10.1063/1.443518

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Depolarized low frequency Raman spectra obtained for molten antimony trichloride are discussed. Measurement has also been performed on the supercooled liquid down to 53.2° below the melting point (tm = 73.4 °C. The experimental results indicate that the spectral contributions, in the range 2–100 cm−1 of Stokes shift from the exciting line are due to: (1) a central Lorentzian line, whose width and intensity are connected to the dynamics of the break-up of intermolecular chlorine bridges; and (2) a solidlike contribution that furnishes an effective density of states, which corresponds to a convolution of ’’acoustical’’ and ’’optical’’ modes in a coupled linear chain structure with middle range order.

Bibliography

Aliotta, F., Maisano, G., Micali, N., Migliardo, P., Vasi, C., Wanderlingh, F., Triolo, R., & Smith, G. P. (1982). Depolarized Raman scattering in normal and supercooled antimony trichloride. The Journal of Chemical Physics, 76(8), 3987â3992.

Authors 8

F. Aliotta (first)
G. Maisano (additional)
N. Micali (additional)
P. Migliardo (additional)
C. Vasi (additional)
F. Wanderlingh (additional)
R. Triolo (additional)
G. P. Smith (additional)

References 32 Referenced 17

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10.1016/S0022-0728(70)80287-X / J. Electroanal. Chem. (1970)
{'key': '2024020922082425800_r8'}
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10.1021/ic50119a014 / Inorg. Chem. (1973)
10.1002/jrs.1250090312 / J. Raman Spectrosc. (1980)
{'key': '2024020922082425800_r11'}
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{'key': '2024020922082425800_r14'}
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Dates

Type	When
Created	22 years, 5 months ago (Feb. 28, 2003, 6:17 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 1:48 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 12:23 a.m.)
Issued	43 years, 4 months ago (April 15, 1982)
Published	43 years, 4 months ago (April 15, 1982)
Published Print	43 years, 4 months ago (April 15, 1982)

Funders 0

None

BibTeX

@article{Aliotta_1982, title={Depolarized Raman scattering in normal and supercooled antimony trichloride}, volume={76}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.443518}, DOI={10.1063/1.443518}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Aliotta, F. and Maisano, G. and Micali, N. and Migliardo, P. and Vasi, C. and Wanderlingh, F. and Triolo, R. and Smith, G. P.}, year={1982}, month=apr, pages={3987–3992} }

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