DOI: 10.1063/1.442217. Conducting complexes of polyphenylene sulfides

Conducting complexes of polyphenylene sulfides

10.1063/1.442217

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Poly(p-phenylene) sulfide, poly(m-phenylene) sulfide, and the newly synthesized polymer poly(thio-2,8-dibenzothiophenediyl) have been treated with strong electron acceptors (AsF5, SbF5) to form conducting complexes with p-type electronic conductivities up to 3 S/cm. Near IR to UV absorption spectra and temperature-dependent conductivity measurements suggest a localization of charge carriers even at high doping levels. Elemental analysis and IR spectroscopy demonstrate that heavy exposure to AsF5 causes substantial changes in the backbone structure of these polymers. The dopant appears to predominantly induce the formation of carbon–carbon bonds bridging the sulfur linkages to form thiophene rings. This chemical modification enhances the conductivity of the complex and, in the case of poly(m-phenylene), is shown to be an actual prerequisite for achieving high conductivity.

Bibliography

Shacklette, L. W., Elsenbaumer, R. L., Chance, R. R., Eckhardt, H., Frommer, J. E., & Baughman, R. H. (1981). Conducting complexes of polyphenylene sulfides. The Journal of Chemical Physics, 75(4), 1919â1927.

Authors 6

L. W. Shacklette (first)
R. L. Elsenbaumer (additional)
R. R. Chance (additional)
H. Eckhardt (additional)
J. E. Frommer (additional)
R. H. Baughman (additional)

References 28 Referenced 191

10.1002/pol.1979.130170404 / J. Polym. Sci. Polym. Lett. Ed. (1979)
10.1016/0379-6779(80)90020-X / Synth. Metals (1980)
10.1016/0379-6779(80)90022-3 / Synth. Metals (1980)
10.1016/0032-3861(79)90002-8 / Polymer (1979)
{'key': '2024020921162780600_r5', 'first-page': '314', 'volume': '25', 'year': '1980', 'journal-title': 'Bull. Am. Phys. Soc.'} / Bull. Am. Phys. Soc. (1980)
{'key': '2024020921162780600_r6'}
{'key': '2024020921162780600_r7'}
{'key': '2024020921162780600_r8'}
10.1021/ma60050a001 / Macromolecules (1976)
{'key': '2024020921162780600_r10', 'first-page': '4982', 'volume': '73', 'year': '1952', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. (1952)
{'key': '2024020921162780600_r11'}
{'key': '2024020921162780600_r12'}
10.1016/B978-0-12-002906-8.50007-X / Appl. Solid State Sci. (1976)
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10.1103/PhysRevLett.40.1197 / Phys. Rev. Lett. (1978)
{'key': '2024020921162780600_r16', 'first-page': '135', 'volume': '35', 'year': '1980', 'journal-title': 'Solid State Commun.'} / Solid State Commun. (1980)
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{'key': '2024020921162780600_r23'}
{'key': '2024020921162780600_r24', 'first-page': '863', 'volume': '43', 'year': '1980', 'journal-title': 'Org. Coat Plast. Chem.'} / Org. Coat Plast. Chem. (1980)
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{'key': '2024020921162780600_r27'}
{'key': '2024020921162780600_r28'}

Dates

Type	When
Created	22 years, 6 months ago (Feb. 28, 2003, 11:03 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 6:04 p.m.)
Indexed	2 months, 1 week ago (June 26, 2025, 1:05 p.m.)
Issued	44 years ago (Aug. 15, 1981)
Published	44 years ago (Aug. 15, 1981)
Published Print	44 years ago (Aug. 15, 1981)

Funders 0

None

BibTeX

@article{Shacklette_1981, title={Conducting complexes of polyphenylene sulfides}, volume={75}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.442217}, DOI={10.1063/1.442217}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Shacklette, L. W. and Elsenbaumer, R. L. and Chance, R. R. and Eckhardt, H. and Frommer, J. E. and Baughman, R. H.}, year={1981}, month=aug, pages={1919–1927} }

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