DOI: 10.1063/1.441398. Dissociation energies of molecules with very heavy atoms from mass spectrometry

Dissociation energies of molecules with very heavy atoms from mass spectrometry

10.1063/1.441398

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

For Pb2 and BiLi, it is shown that relativistic effects yield large spin-orbit splittings and thus reduce the electronic partition function by significant amount. Since the partition function is required for dissociation energy calculations from mass spectrometric data, caution is advised in choosing the electronic partition function.

Bibliography

Pitzer, K. S. (1981). Dissociation energies of molecules with very heavy atoms from mass spectrometry. The Journal of Chemical Physics, 74(5), 3078â3079.

Authors 1

Kenneth S. Pitzer (first)

References 4 Referenced 12

10.1063/1.432036 / J. Chem. Phys. (1976)
10.1063/1.440200 / J. Chem. Phys. (1980)
{'key': '2024020920143706300_r3'}
10.1063/1.435335 / J. Chem. Phys. (1977)

Dates

Type	When
Created	22 years, 6 months ago (Feb. 28, 2003, 10:46 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 5:19 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 11:43 a.m.)
Issued	44 years, 6 months ago (March 1, 1981)
Published	44 years, 6 months ago (March 1, 1981)
Published Print	44 years, 6 months ago (March 1, 1981)

Funders 0

None

BibTeX

@article{Pitzer_1981, title={Dissociation energies of molecules with very heavy atoms from mass spectrometry}, volume={74}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.441398}, DOI={10.1063/1.441398}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Pitzer, Kenneth S.}, year={1981}, month=mar, pages={3078–3079} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T16:43:41Z",
    "timestamp": 1707583421663
  },
  "reference-count": 4,
  "publisher": "AIP Publishing",
  "issue": "5",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1981,
        3,
        1
      ]
    ]
  },
  "abstract": "<jats:p>For Pb2 and BiLi, it is shown that relativistic effects yield large spin-orbit splittings and thus reduce the electronic partition function by significant amount. Since the partition function is required for dissociation energy calculations from mass spectrometric data, caution is advised in choosing the electronic partition function.</jats:p>",
  "DOI": "10.1063/1.441398",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2003,
        2,
        28
      ]
    ],
    "date-time": "2003-02-28T15:46:48Z",
    "timestamp": 1046447208000
  },
  "page": "3078-3079",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 12,
  "title": "Dissociation energies of molecules with very heavy atoms from mass spectrometry",
  "prefix": "10.1063",
  "volume": "74",
  "author": [
    {
      "given": "Kenneth S.",
      "family": "Pitzer",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemistry and Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020920143706300_r1",
      "doi-asserted-by": "crossref",
      "first-page": "4027",
      "DOI": "10.1063/1.432036",
      "volume": "64",
      "year": "1976",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020920143706300_r2",
      "doi-asserted-by": "crossref",
      "first-page": "1406",
      "DOI": "10.1063/1.440200",
      "volume": "73",
      "year": "1980",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020920143706300_r3"
    },
    {
      "key": "2024020920143706300_r4",
      "doi-asserted-by": "crossref",
      "first-page": "3405",
      "DOI": "10.1063/1.435335",
      "volume": "67",
      "year": "1977",
      "journal-title": "J. Chem. Phys."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/74/5/3078/18927154/3078_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/74/5/3078/18927154/3078_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T22:19:42Z",
    "timestamp": 1707517182000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/74/5/3078/217175/Dissociation-energies-of-molecules-with-very-heavy"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1981,
        3,
        1
      ]
    ]
  },
  "references-count": 4,
  "journal-issue": {
    "issue": "5",
    "published-print": {
      "date-parts": [
        [
          1981,
          3,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.441398",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1981,
        3,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1981,
        3,
        1
      ]
    ]
  }
}