DOI: 10.1063/1.441180. Surface-enhanced Raman spectroscopy of CO adsorbed on colloidal silver particles

Surface-enhanced Raman spectroscopy of CO adsorbed on colloidal silver particles

10.1063/1.441180

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The surface-enhanced Raman spectrum of CO adsorbed on colloidal silver particles of about 100 Å diameter is reported. The spectrum resembles that observed for CO adsorbed on vapor-deposited silver. Only three strong Raman lines appear, at 2113, 160, and 64 cm−1. These are assigned, respectively, to the CO stretching, Ag–C stretching, and AgCO bending vibrations. The excitation profile of the 2113 cm−1 line follows closely the plasmon absorption spectrum of the silver colloid, increasing as one goes from the red to the violet; that of the 160 cm−1 line shows a more gradual increase in the same direction. The two types of behavior are accounted for by means of a model which considers the enhancement of the Raman signal to be due to coupling of the adsorbate vibration with the conduction–electron surface plasma mode through a charge transfer from the adsorbate to the metal, synchronous with the vibration. The two types of excitation profile are generated by assuming that for the AgC vibration, positive displacement of the normal coordinate produces charge injection into the metal while for the CO vibration, charge is withdrawn as the CO bond is elongated.

Bibliography

Abe, H., Manzel, K., Schulze, W., Moskovits, M., & DiLella, D. P. (1981). Surface-enhanced Raman spectroscopy of CO adsorbed on colloidal silver particles. The Journal of Chemical Physics, 74(2), 792â797.

Authors 5

H. Abe (first)
K. Manzel (additional)
W. Schulze (additional)
M. Moskovits (additional)
D. P. DiLella (additional)

References 19 Referenced 78

10.1016/0009-2614(74)80459-8 / Chem. Phys. Lett. (1974)
10.1016/S0022-0728(77)80224-6 / J. Electroanal. Chem. (1977)
10.1016/0039-6028(80)90270-8 / Surf. Sci. (1980)
10.1063/1.430708 / J. Chem. Phys. (1975)
10.1016/0584-8539(79)80141-5 / Spectrochim. Acta Part A (1979)
{'key': '2024020920082315400_r3b'}
10.1063/1.437095 / J. Chem. Phys. (1978)
10.1039/f29797500790 / J. Chem. Soc. Faraday Trans. 2 (1979)
10.1116/1.569981 / J. Vac. Sci. Technol. (1979)
10.1016/0301-0104(80)80024-3 / Chem. Phys. (1980)
10.1063/1.440710 / J. Chem. Phys. (1980)
10.1016/0038-1098(79)90997-9 / Solid State Commun. (1979)
10.1103/PhysRevB.8.3689 / Phys. Rev. B (1973)
10.1007/BF01392504 / Z. Phys. (1970)
10.1039/f29736900065 / J. Chem. Soc. Faraday Trans. 2 (1973)
{'key': '2024020920082315400_r12'}
{'key': '2024020920082315400_r13'}
10.1016/0039-6028(78)90263-7 / Surf. Sci. (1978)
10.1016/0039-6028(79)90578-8 / Surf. Sci. (1979)

Dates

Type	When
Created	22 years, 6 months ago (Feb. 28, 2003, 10:46 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 5:14 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 4:52 a.m.)
Issued	44 years, 7 months ago (Jan. 15, 1981)
Published	44 years, 7 months ago (Jan. 15, 1981)
Published Print	44 years, 7 months ago (Jan. 15, 1981)

Funders 0

None

BibTeX

@article{Abe_1981, title={Surface-enhanced Raman spectroscopy of CO adsorbed on colloidal silver particles}, volume={74}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.441180}, DOI={10.1063/1.441180}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Abe, H. and Manzel, K. and Schulze, W. and Moskovits, M. and DiLella, D. P.}, year={1981}, month=jan, pages={792–797} }

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