DOI: 10.1063/1.441161. The structure of electrolytes at charged surfaces: The primitive model

The structure of electrolytes at charged surfaces: The primitive model

10.1063/1.441161

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The effects of ion size on the structure of a primitive model electrical double layer at a charged surface is considered using the integral equation method based on a combined hypernetted chain and mean spherical approximation (HNC/MSA). The HNC/MSA is shown to be a nonlinear weak field approximation. The contact values of the surface ion distribution functions are shown to have the correct quadratic dependence on the surface charge density, An analytical comparison between the HNC/MSA and earlier work based on the modified Poisson–Boltzmann equation is given.

Bibliography

Carnie, S. L., Chan, D. Y. C., Mitchell, D. J., & Ninham, B. W. (1981). The structure of electrolytes at charged surfaces: The primitive model. The Journal of Chemical Physics, 74(2), 1472â1478.

Authors 4

Steven L. Carnie (first)
Derek Y. C. Chan (additional)
D. John Mitchell (additional)
Barry W. Ninham (additional)

References 18 Referenced 146

10.1039/f29787401670 / J. Chem. Soc. Faraday Trans. 2 (1978)
10.1016/0009-2614(79)87041-4 / Chem. Phys. Lett. (1979)
10.1080/00018737900101365 / Adv. Phys. (1979)
10.1103/PhysRevA.15.2566 / Phys. Rev. A (1977)
10.1063/1.435224 / J. Chem. Phys. (1977)
10.1016/S0022-0728(78)80228-9 / J. Electroanal. Chem. (1978)
10.1016/S0022-0728(79)80459-3 / J. Electroanal. Chem. (1979)
10.1063/1.1677644 / J. Chem. Phys. (1972)
10.1063/1.1677645 / J. Chem. Phys. (1972)
{'key': '2024020920210295900_r8', 'first-page': '321', 'volume': '8', 'year': '1963', 'journal-title': 'Phys. Rev. Lett.'} / Phys. Rev. Lett. (1963)
{'key': '2024020920210295900_r9'}
10.1063/1.1731401 / J. Chem. Phys. (1960)
10.1080/00268977200101421 / Mol. Phys. (1972)
{'key': '2024020920210295900_r12'}
10.1039/df9664200069 / Discuss. Faraday Soc. (1966)
10.1016/0009-2614(79)87078-5 / Chem. Phys. Lett. (1979)
10.1063/1.1748352 / J. Chem. Phys. (1951)
{'key': '2024020920210295900_r16'}

Dates

Type	When
Created	22 years, 5 months ago (Feb. 28, 2003, 10:46 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 5:24 p.m.)
Indexed	2 weeks, 3 days ago (Aug. 7, 2025, 4:28 p.m.)
Issued	44 years, 7 months ago (Jan. 15, 1981)
Published	44 years, 7 months ago (Jan. 15, 1981)
Published Print	44 years, 7 months ago (Jan. 15, 1981)

Funders 0

None

BibTeX

@article{Carnie_1981, title={The structure of electrolytes at charged surfaces: The primitive model}, volume={74}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.441161}, DOI={10.1063/1.441161}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Carnie, Steven L. and Chan, Derek Y. C. and Mitchell, D. John and Ninham, Barry W.}, year={1981}, month=jan, pages={1472–1478} }

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