Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

The recently reported generalization of Slater’s theory of unimolecular reactions has been applied to the problem of atomic desorption from a crystalline solid (specifically, helium from solid xenon). Using this formalism we are able to calculate the temperature and surface coverage dependence of the desorption rate constant as well as to observe the extent to which the rate is sensitive to the structure of the crystal substrate. In addition, our results suggest that a cooperative desorption mechanism may become important at low surface temperatures for some systems.

Bibliography

Adams, J. E., & Doll, J. D. (1981). Desorption from solid surfaces via generalized Slater theory. The Journal of Chemical Physics, 74(2), 1467–1471.

Authors 2
  1. John E. Adams (first)
  2. Jimmie D. Doll (additional)
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Dates
Type When
Created 22 years, 5 months ago (Feb. 28, 2003, 10:46 a.m.)
Deposited 1 year, 6 months ago (Feb. 9, 2024, 5:18 p.m.)
Indexed 11 months ago (Sept. 19, 2024, 10:55 a.m.)
Issued 44 years, 7 months ago (Jan. 15, 1981)
Published 44 years, 7 months ago (Jan. 15, 1981)
Published Print 44 years, 7 months ago (Jan. 15, 1981)
Funders 0

None

@article{Adams_1981, title={Desorption from solid surfaces via generalized Slater theory}, volume={74}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.441160}, DOI={10.1063/1.441160}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Adams, John E. and Doll, Jimmie D.}, year={1981}, month=jan, pages={1467–1471} }