DOI: 10.1063/1.441104. On the anisotropic energy transfer to random acceptors

On the anisotropic energy transfer to random acceptors

10.1063/1.441104

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We present exact expressions for the ensemble averaged decay of the excitation of a donor molecule, due to the energy transfer via anisotropic dipolar interactions to acceptors distributed randomly on a lattice. We compare in two special cases the approximate, Förster-type expressions, valid for low acceptor concentrations and long times, with the exact results: in the case of a completely random angular distribution and in case of a preferential orientation. The connection to the decay law for isotropic interactions [Blumen and Manz, J. Chem. Phys. 71, 4694 (1979)] is also presented. Whereas the approximate expressions show similar qualitative behavior in all cases, their regions of validity (compared to the exact results) differ considerably; the difference is especially large for the decay due to acceptors which are randomly distributed on the lattice but are orientationally ordered.

Bibliography

Blumen, A. (1981). On the anisotropic energy transfer to random acceptors. The Journal of Chemical Physics, 74(12), 6926â6933.

Authors 1

Alexander Blumen (first)

References 29 Referenced 40

10.1515/zna-1949-0501 / Z. Naturforsoh. Teil A (1949)
10.1063/1.1699044 / J. Chem. Phys. (1953)
{'key': '2024020920405496500_r3', 'first-page': '485', 'volume': '28', 'year': '1955', 'journal-title': 'Zh. Eksp. Teor. Fiz.'} / Zh. Eksp. Teor. Fiz. (1955)
{'key': '2024020920405496500_r3a', 'first-page': '317', 'volume': '1', 'year': '1955', 'journal-title': 'Sov. Phys. JETP'} / Sov. Phys. JETP (1955)
{'key': '2024020920405496500_r4', 'first-page': '606', 'volume': '12', 'year': '1962', 'journal-title': 'Opt. Spektrosc.'} / Opt. Spektrosc. (1962)
{'key': '2024020920405496500_r4a', 'first-page': '337', 'volume': '12', 'year': '1962', 'journal-title': 'Opt. Spectrosc.'} / Opt. Spectrosc. (1962)
10.1063/1.1725941 / J. Chem. Phys. (1964)
10.1063/1.1697063 / J. Chem. Phys. (1965)
10.1063/1.1669461 / J. Chem. Phys. (1968)
{'key': '2024020920405496500_r8', 'first-page': '3185', 'volume': '13', 'year': '1971', 'journal-title': 'Fiz. Tverd. Tela'} / Fiz. Tverd. Tela (1971)
{'key': '2024020920405496500_r8a', 'first-page': '2679', 'volume': '13', 'year': '1972', 'journal-title': 'Sov. Phys. Solid State'} / Sov. Phys. Solid State (1972)
{'key': '2024020920405496500_r9', 'first-page': '2199', 'volume': '14', 'year': '1972', 'journal-title': 'Fiz. Tverd. Tela'} / Fiz. Tverd. Tela (1972)
{'key': '2024020920405496500_r9a', 'first-page': '1906', 'volume': '14', 'year': '1973', 'journal-title': 'Sov. Phys. Solid State'} / Sov. Phys. Solid State (1973)
10.1063/1.1680599 / J. Chem. Phys. (1973)
10.1103/PhysRevB.16.4642 / Phys. Rev. B (1977)
10.1063/1.438253 / J. Chem. Phys. (1979)
10.1143/PTP.35.357 / Prog. Theor. Phys. (1966)
{'key': '2024020920405496500_r14', 'first-page': '89', 'volume': '23', 'year': '1977', 'journal-title': 'Acta Phys. Chem. Szeged.'} / Acta Phys. Chem. Szeged. (1977)
{'key': '2024020920405496500_r15'}
10.1146/annurev.bi.47.070178.004131 / Ann. Rev. Biochem. (1978)
10.1016/S0006-3495(79)85243-1 / Biophys. J. (1979)
10.1016/0031-8914(68)90090-6 / Physica (Utrecht) (1968)
{'key': '2024020920405496500_r19', 'first-page': '57', 'volume': '5', 'year': '1971', 'journal-title': 'Phys. Norv.'} / Phys. Norv. (1971)
10.1016/0301-0104(77)87053-5 / Chem. Phys. (1977)
10.1063/1.437975 / J. Chem. Phys. (1979)
10.1063/1.437999 / J. Chem. Phys. (1979)
10.1063/1.439023 / J. Chem. Phys. (1980)
10.1063/1.439408 / J. Chem. Phys. (1980)
{'key': '2024020920405496500_r25'}

Dates

Type	When
Created	22 years, 6 months ago (Feb. 28, 2003, 10:46 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 5:39 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 10:21 a.m.)
Issued	44 years, 2 months ago (June 15, 1981)
Published	44 years, 2 months ago (June 15, 1981)
Published Print	44 years, 2 months ago (June 15, 1981)

Funders 0

None

BibTeX

@article{Blumen_1981, title={On the anisotropic energy transfer to random acceptors}, volume={74}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.441104}, DOI={10.1063/1.441104}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Blumen, Alexander}, year={1981}, month=jun, pages={6926–6933} }

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