Abstract
The isotopic exchange between CO chemisorbed on Ni(100) and CO(g) has been studied using thermal desorption spectroscopy. Rapid isotopic exchange occurs at low crystal temperatures, and presumably involves low adsorption energy CO states which are present at high CO coverages on the Ni(100). Exchange is accompanied by rapid equilibration of exchanged CO throughout the entire CO layer.
References
13
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Dates
Type | When |
---|---|
Created | 22 years, 5 months ago (Feb. 28, 2003, 10:31 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 9, 2024, 5 p.m.) |
Indexed | 2 months ago (June 27, 2025, 3:44 p.m.) |
Issued | 44 years, 9 months ago (Nov. 15, 1980) |
Published | 44 years, 9 months ago (Nov. 15, 1980) |
Published Print | 44 years, 9 months ago (Nov. 15, 1980) |
@article{Yates_1980, title={Carbon monoxide chemisorption on Ni(100)—direct detection of adsorbate–adsorbate interactions by desorption kinetic measurements}, volume={73}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.439968}, DOI={10.1063/1.439968}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Yates, John T. and Goodman, D. Wayne}, year={1980}, month=nov, pages={5371–5375} }