Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

Experimental techniques are described for preparation of three layer sandwich matrices on evaporated metal surfaces at 4 °K. These structures enable molecule–surface interactions to be studied as a function of distance to the surface. Classical electromagnetic energy transfer theory approximately agrees with experiment for the system pyrazine–silver at distances greater than about 125 Å. Below 125 Å, there is some evidence that either classical theory fails, or that surface structure causes slower energy transfer rates. Classical electromagnetic energy transfer theory is shown to imply qualitatively different analytical behavior at long distance (≳400 Å) than at short distances.

Bibliography

Rossetti, R., & Brus, L. E. (1980). Time resolved molecular electronic energy transfer into a silver surface. The Journal of Chemical Physics, 73(1), 572–577.

Authors 2
  1. R. Rossetti (first)
  2. L. E. Brus (additional)
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Dates
Type When
Created 22 years, 6 months ago (Feb. 28, 2003, 10:31 a.m.)
Deposited 1 year, 6 months ago (Feb. 9, 2024, 4:24 p.m.)
Indexed 1 year, 6 months ago (Feb. 11, 2024, 12:22 a.m.)
Issued 45 years, 1 month ago (July 1, 1980)
Published 45 years, 1 month ago (July 1, 1980)
Published Print 45 years, 1 month ago (July 1, 1980)
Funders 0

None

@article{Rossetti_1980, title={Time resolved molecular electronic energy transfer into a silver surface}, volume={73}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.439857}, DOI={10.1063/1.439857}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Rossetti, R. and Brus, L. E.}, year={1980}, month=jul, pages={572–577} }