DOI: 10.1063/1.439547. Ultraviolet resonance Raman excitation profiles of pyrimidine nucleotides

Ultraviolet resonance Raman excitation profiles of pyrimidine nucleotides

10.1063/1.439547

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A semiempirical theoretical method for calculating the resonant Raman excitation profiles (RREP) from the measured absorption profile is developed and applied to measurements on pyrimidine mononucleotides. The method is general and provides a way of checking the consistency of a measured RREP with a measured absorption profile. From this treatment one obtains Δej, the shift in the equilibrium position of the normal coordinate Qj when the molecule is excited to the eth (resonant) electronic state. This quantity is useful in the estimation of the excited state geometry. Some error in our calculated values of Δej may result because changes in the excited state normal-mode frequencies have not been included in our evaluation of the Franck–Condon factors.

Bibliography

Blazej, D. C., & Peticolas, W. L. (1980). Ultraviolet resonance Raman excitation profiles of pyrimidine nucleotides. The Journal of Chemical Physics, 72(5), 3134â3142.

Authors 2

Daniel C. Blazej (first)
Warner L. Peticolas (additional)

References 24 Referenced 96

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10.1016/0022-2852(74)90236-7 / J. Mol. Spectrosc. (1974)
10.1002/jrs.1250060602 / J. Raman Spectrosc. (1977)
10.1063/1.433867 / J. Chem. Phys. (1977)
{'key': '2024020918554319400_r7'}
10.1002/bip.1978.360170518 / Biopolymers (1978)
10.1016/0009-2614(79)80723-X / Chem. Phys. Lett. (1979)
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{'key': '2024020918554319400_r12'}
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Dates

Type	When
Created	22 years, 6 months ago (Feb. 28, 2003, 3 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 3:57 p.m.)
Indexed	2 days, 19 hours ago (Sept. 3, 2025, 6:13 a.m.)
Issued	45 years, 6 months ago (March 1, 1980)
Published	45 years, 6 months ago (March 1, 1980)
Published Print	45 years, 6 months ago (March 1, 1980)

Funders 0

None

BibTeX

@article{Blazej_1980, title={Ultraviolet resonance Raman excitation profiles of pyrimidine nucleotides}, volume={72}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.439547}, DOI={10.1063/1.439547}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Blazej, Daniel C. and Peticolas, Warner L.}, year={1980}, month=mar, pages={3134–3142} }

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