DOI: 10.1063/1.438812. Franck–Condon effects in resonance Raman spectra and excitation profiles

Franck–Condon effects in resonance Raman spectra and excitation profiles

10.1063/1.438812

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Resonance Raman spectra and excitation profiles are calculated for totally symmetric vibrations not involved in vibronic coupling and thus deriving all their intensity from Franck–Condon effects. Theoretical results are derived for harmonic oscillators undergoing displacements and frequency shifts upon electronic excitation of the molecule. The model does not only consider the effect of interference between several totally symmetric modes but also includes a number of basic refinements absent from most previous treatments such as inhomogeneous line broadening, perturbation of a weak resonance transition by the preresonance spectrum of a strong neighboring transition, and normal coordinate rotation (Dushinsky effect). The model calculations are used to interpret observed Raman spectra and excitation profiles of totally symmetric modes in the chromate ion and the β-carotene molecule.

Bibliography

Siebrand, W., & Zgierski, M. Z. (1979). FranckâCondon effects in resonance Raman spectra and excitation profiles. The Journal of Chemical Physics, 71(9), 3561â3569.

Authors 2

Willem Siebrand (first)
Marek Z. Zgierski (additional)

References 34 Referenced 127

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{'key': '2024020918224116100_r10', 'first-page': '293', 'volume': '109', 'year': '1973', 'journal-title': 'Usp. Viz. Nauk'} / Usp. Viz. Nauk (1973)
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{'key': '2024020918224116100_r21a', 'first-page': '549', 'volume': '20', 'year': '1966'} (1966)
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Dates

Type	When
Created	22 years, 5 months ago (Feb. 27, 2003, 4:39 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 3:26 p.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 2:34 a.m.)
Issued	45 years, 9 months ago (Nov. 1, 1979)
Published	45 years, 9 months ago (Nov. 1, 1979)
Published Print	45 years, 9 months ago (Nov. 1, 1979)

Funders 0

None

BibTeX

@article{Siebrand_1979, title={Franck–Condon effects in resonance Raman spectra and excitation profiles}, volume={71}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.438812}, DOI={10.1063/1.438812}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Siebrand, Willem and Zgierski, Marek Z.}, year={1979}, month=nov, pages={3561–3569} }

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