Abstract
We extend Tachiya’s method for treating totally diffusion-controlled recombination of a pair of particles to partially diffusion-controlled recombination. The differential equation satisfied by the survival probability of the pair is derived, and solved for several cases of practical interest. Recent experiments on the solvated electron yield in liquid ammonia are analyzed by use of the present theory. It is confirmed that the rather high yield of solvated electrons in irratiated liquid ammonia is due to the slowness of the recombination reaction e−s+NH+4.
References
28
Referenced
268
10.1103/PhysRev.54.554
/ Phys. Rev. (1938)10.1063/1.1700385
/ J. Chem. Phys. (1952)10.1063/1.1841121
/ J. Chem. Phys. (1967)10.1246/bcsj.41.304
/ Bull. Chem. Soc. Jpn. (1968)10.1063/1.1673597
/ J. Chem. Phys. (1970)10.1063/1.1677641
/ J. Chem. Phys. (1972)10.1063/1.436920
/ J. Chem. Phys. (1978)10.1063/1.437238
/ J. Chem. Phys. (1979){'key': '2024020918105731000_r8', 'first-page': '2021', 'volume': '40', 'year': '1979', 'journal-title': 'J. Chem. Phys.'}
/ J. Chem. Phys. (1979){'key': '2024020918105731000_r9'}
10.1039/dc9776300055
/ Faraday Discuss. Chem. Soc. (1977)10.1063/1.1681104
/ J. Chem. Phys. (1974)10.1139/v73-544
/ Can. J. Chem. (1973)10.1063/1.1669967
/ J. Chem. Phys. (1968){'key': '2024020918105731000_r11a'}
10.1063/1.1677875
/ J. Chem. Phys. (1972)10.1063/1.436796
/ J. Chem. Phys. (1978){'key': '2024020918105731000_r13'}
10.1063/1.435636
/ J. Chem. Phys. (1978){'key': '2024020918105731000_r15', 'first-page': '129', 'volume': '1', 'year': '1961', 'journal-title': 'Prog. Reac. Kinet.'}
/ Prog. Reac. Kinet. (1961)10.1039/tf9676301712
/ J. Chem. Soc. Faraday Trans. (1967){'key': '2024020918105731000_r17'}
{'key': '2024020918105731000_r18', 'first-page': '199', 'volume': '5', 'year': '1974', 'journal-title': 'Radiat. Res. Rev.'}
/ Radiat. Res. Rev. (1974){'key': '2024020918105731000_r19'}
10.1021/j100601a008
/ J. Phys. Chem. (1974)10.1039/f19747000718
/ J. Chem. Soc. Faraday Trans. I (1974)10.1139/v77-297
/ Can. J. Chem. (1977){'key': '2024020918105731000_r21'}
Dates
Type | When |
---|---|
Created | 22 years, 6 months ago (Feb. 27, 2003, 4:39 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 9, 2024, 3:14 p.m.) |
Indexed | 1 month, 2 weeks ago (July 16, 2025, 9:29 a.m.) |
Issued | 46 years, 1 month ago (Aug. 1, 1979) |
Published | 46 years, 1 month ago (Aug. 1, 1979) |
Published Print | 46 years, 1 month ago (Aug. 1, 1979) |
@article{Sano_1979, title={Partially diffusion-controlled recombination}, volume={71}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.438427}, DOI={10.1063/1.438427}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Sano, Hisatake and Tachiya, M.}, year={1979}, month=aug, pages={1276–1282} }