DOI: 10.1063/1.438153. The structure of the (√3×√3) <i>R</i>30° sulfur overlayer on the iridium (111) surface

The structure of the (√3×√3) R30° sulfur overlayer on the iridium (111) surface

10.1063/1.438153

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

At one-third of a monolayer coverage, sulfur forms an ordered (√3×√3) R30° superstructure on the Ir (111) surface. A comparison between dynamic calculations of the intensity–voltage profiles of diffracted beams for different assumed surface geometries and measured low-energy electron diffraction beam profiles demonstrates that the sulfur adatoms occupy one of the two inequivalent types of threefold hollow sites. In particular, the sulfur resides in the threefold sites directly above a vacancy in the second substrate layer with an interlayer spacing of 1.65 Å corresponding to an Ir–S bond length of 2.28 Å.

Bibliography

Chan, C.-M., & Weinberg, W. H. (1979). The structure of the (â3Ãâ3) R30Â° sulfur overlayer on the iridium (111) surface. The Journal of Chemical Physics, 71(10), 3988â3990.

Authors 2

C.-M. Chan (first)
W. H. Weinberg (additional)

References 13 Referenced 40

10.1103/PhysRevLett.32.1182 / Phys. Rev. Lett. (1974)
10.1103/PhysRevLett.30.17 / Phys. Rev. Lett. (1973)
10.1088/0022-3719/11/21/007 / J. Phys. C (1978)
10.1063/1.431970 / J. Chem. Phys. (1976)
10.1016/0039-6028(77)90027-9 / Surf. Sci. (1977)
{'key': '2024020918235446100_r6'}
10.1088/0305-4608/2/6/008 / J. Phys. F (1972)
10.1103/PhysRevLett.31.540 / Phys. Rev. Lett. (1973)
10.1016/0039-6028(79)90212-7 / Surf. Sci. (1979)
10.1016/0039-6028(77)90428-9 / Surf. Sci. (1977)
{'key': '2024020918235446100_r11'}
10.1021/ja00765a026 / J. Am. Chem. Soc. (1972)
10.1016/S0022-328X(00)88728-8 / J. Organometal. Chem. (1975)

Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 4:39 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 3:27 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 6:06 p.m.)
Issued	45 years, 9 months ago (Nov. 15, 1979)
Published	45 years, 9 months ago (Nov. 15, 1979)
Published Print	45 years, 9 months ago (Nov. 15, 1979)

Funders 0

None

BibTeX

@article{Chan_1979, title={The structure of the (√3×√3) R30° sulfur overlayer on the iridium (111) surface}, volume={71}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.438153}, DOI={10.1063/1.438153}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Chan, C.-M. and Weinberg, W. H.}, year={1979}, month=nov, pages={3988–3990} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T23:06:18Z",
    "timestamp": 1707519978153
  },
  "reference-count": 13,
  "publisher": "AIP Publishing",
  "issue": "10",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1979,
        11,
        15
      ]
    ]
  },
  "abstract": "<jats:p>At one-third of a monolayer coverage, sulfur forms an ordered (\u221a3\u00d7\u221a3) R30\u00b0 superstructure on the Ir (111) surface. A comparison between dynamic calculations of the intensity\u2013voltage profiles of diffracted beams for different assumed surface geometries and measured low-energy electron diffraction beam profiles demonstrates that the sulfur adatoms occupy one of the two inequivalent types of threefold hollow sites. In particular, the sulfur resides in the threefold sites directly above a vacancy in the second substrate layer with an interlayer spacing of 1.65 \u00c5 corresponding to an Ir\u2013S bond length of 2.28 \u00c5.</jats:p>",
  "DOI": "10.1063/1.438153",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2003,
        2,
        27
      ]
    ],
    "date-time": "2003-02-27T21:39:21Z",
    "timestamp": 1046381961000
  },
  "page": "3988-3990",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 40,
  "title": "The structure of the (\u221a3\u00d7\u221a3) <i>R</i>30\u00b0 sulfur overlayer on the iridium (111) surface",
  "prefix": "10.1063",
  "volume": "71",
  "author": [
    {
      "given": "C.-M.",
      "family": "Chan",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125"
        }
      ]
    },
    {
      "given": "W. H.",
      "family": "Weinberg",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020918235446100_r1",
      "doi-asserted-by": "crossref",
      "first-page": "1182",
      "DOI": "10.1103/PhysRevLett.32.1182",
      "volume": "32",
      "year": "1974",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020918235446100_r2",
      "doi-asserted-by": "crossref",
      "first-page": "17",
      "DOI": "10.1103/PhysRevLett.30.17",
      "volume": "30",
      "year": "1973",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020918235446100_r3",
      "doi-asserted-by": "crossref",
      "first-page": "4271",
      "DOI": "10.1088/0022-3719/11/21/007",
      "volume": "11",
      "year": "1978",
      "journal-title": "J. Phys. C"
    },
    {
      "key": "2024020918235446100_r4",
      "doi-asserted-by": "crossref",
      "first-page": "250",
      "DOI": "10.1063/1.431970",
      "volume": "64",
      "year": "1976",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020918235446100_r5",
      "doi-asserted-by": "crossref",
      "first-page": "394",
      "DOI": "10.1016/0039-6028(77)90027-9",
      "volume": "66",
      "year": "1977",
      "journal-title": "Surf. Sci."
    },
    {
      "key": "2024020918235446100_r6"
    },
    {
      "key": "2024020918235446100_r7",
      "doi-asserted-by": "crossref",
      "first-page": "1033",
      "DOI": "10.1088/0305-4608/2/6/008",
      "volume": "2",
      "year": "1972",
      "journal-title": "J. Phys. F"
    },
    {
      "key": "2024020918235446100_r8",
      "doi-asserted-by": "crossref",
      "first-page": "540",
      "DOI": "10.1103/PhysRevLett.31.540",
      "volume": "31",
      "year": "1973",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020918235446100_r9",
      "doi-asserted-by": "crossref",
      "first-page": "577",
      "DOI": "10.1016/0039-6028(79)90212-7",
      "volume": "82",
      "year": "1979",
      "journal-title": "Surf. Sci."
    },
    {
      "key": "2024020918235446100_r10",
      "doi-asserted-by": "crossref",
      "first-page": "61",
      "DOI": "10.1016/0039-6028(77)90428-9",
      "volume": "62",
      "year": "1977",
      "journal-title": "Surf. Sci."
    },
    {
      "key": "2024020918235446100_r11"
    },
    {
      "key": "2024020918235446100_r12",
      "doi-asserted-by": "crossref",
      "first-page": "3413",
      "DOI": "10.1021/ja00765a026",
      "volume": "94",
      "year": "1972",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020918235446100_r13",
      "doi-asserted-by": "crossref",
      "first-page": "26",
      "DOI": "10.1016/S0022-328X(00)88728-8",
      "volume": "94",
      "year": "1975",
      "journal-title": "J. Organometal. Chem."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/71/10/3988/18919393/3988_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/71/10/3988/18919393/3988_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T20:27:35Z",
    "timestamp": 1707510455000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/71/10/3988/530140/The-structure-of-the-3-3-R30-sulfur-overlayer-on"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1979,
        11,
        15
      ]
    ]
  },
  "references-count": 13,
  "journal-issue": {
    "issue": "10",
    "published-print": {
      "date-parts": [
        [
          1979,
          11,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.438153",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1979,
        11,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1979,
        11,
        15
      ]
    ]
  }
}