Abstract
The species ArCO2 produced by adiabatic expansion is structurally characterized by molecular beam electric resonance spectroscopy. ArCO2 is shown to have C2v symmetry. The spectroscopic constants obtained are: The derived structural constants for ArCO2 are: Comparison is made with a number of proposed Ar–CO2 intermolecular potentials. The determined force constants are shown to be poorly fitted by a spherical argon–oxygen interaction.
References
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Dates
Type | When |
---|---|
Created | 22 years, 6 months ago (Feb. 27, 2003, 5:52 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 9, 2024, 2:50 p.m.) |
Indexed | 1 month, 3 weeks ago (July 2, 2025, 2:11 p.m.) |
Issued | 46 years, 3 months ago (May 1, 1979) |
Published | 46 years, 3 months ago (May 1, 1979) |
Published Print | 46 years, 3 months ago (May 1, 1979) |
@article{Steed_1979, title={Determination of the structure of ArCO2 by radio frequency and microwave spectroscopy}, volume={70}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.438033}, DOI={10.1063/1.438033}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Steed, J. M. and Dixon, T. A. and Klemperer, W.}, year={1979}, month=may, pages={4095–4100} }