DOI: 10.1063/1.438029. High temperature expansion for the Gaussian core model

High temperature expansion for the Gaussian core model

10.1063/1.438029

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Exact series coefficients through eighth order are reported for the high temperature expansion of the Gaussian core model free energy. Although this expanison has a vanishing radius of convergence it can be summed by a Borel integral transform. It is demonstrated that this Borel transform has an intimate connection to ’’crystallites’’ in the stable fluid phase which causes it to display a replica of the distribution function for large crystallites. This last observation permits implementation of a transform subtractive procedure which generates metastable extensions of fluid properties into the supercooled regime below the thermodynamic freezing temperature.

Bibliography

Stillinger, F. H. (1979). High temperature expansion for the Gaussian core model. The Journal of Chemical Physics, 70(9), 4067â4075.

Authors 1

Frank H. Stillinger (first)

References 15 Referenced 28

10.1063/1.432891 / J. Chem. Phys. (1976)
10.1063/1.436191 / J. Chem. Phys. (1978)
{'key': '2024020917461902700_r2a', 'first-page': '1074E', 'volume': '70', 'year': '1979', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1979)
{'key': '2024020917461902700_r3'}
{'key': '2024020917461902700_r4'}
10.1063/1.523395 / J. Math. Phys. (1977)
10.1103/PhysRevLett.39.95 / Phys. Rev. Lett. (1977)
{'key': '2024020917461902700_r7'}
{'key': '2024020917461902700_r8', 'first-page': '1415', 'volume': '18', 'year': '1964', 'journal-title': 'Soviet Physics JETP'} / Soviet Physics JETP (1964)
10.1103/PhysicsPhysiqueFizika.3.255 / Physics (1967)
10.1103/PhysRevLett.37.639 / Phys. Rev. Lett. (1976)
10.1007/BF01032094 / Theor. Math. Phys. (1976)
10.1063/1.1776907 / J. Chem. Phys. (1963)
{'key': '2024020917461902700_r13'}
{'key': '2024020917461902700_r14'}

Dates

Type	When
Created	22 years, 5 months ago (Feb. 27, 2003, 5:52 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 2:42 p.m.)
Indexed	4 months, 3 weeks ago (March 27, 2025, 2:39 p.m.)
Issued	46 years, 3 months ago (May 1, 1979)
Published	46 years, 3 months ago (May 1, 1979)
Published Print	46 years, 3 months ago (May 1, 1979)

Funders 0

None

BibTeX

@article{Stillinger_1979, title={High temperature expansion for the Gaussian core model}, volume={70}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.438029}, DOI={10.1063/1.438029}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Stillinger, Frank H.}, year={1979}, month=may, pages={4067–4075} }

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