DOI: 10.1063/1.437604. Catalytic decomposition of formaldehyde on single rhodium atoms

Catalytic decomposition of formaldehyde on single rhodium atoms

10.1063/1.437604

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The interaction of H2CO with alumina-supported Rh has been studied by transmission infrared spectroscopy. It has been shown that isolated Rh atoms catalyze the decomposition of H2CO to produce carbonyl hydride species HxRh–CO (x=1,2). Species of the type Rh(HCO) and Rh(HCOH) are not observed to form in detectable amounts. Hydride bonding to rhodium carbonyl species is associated with electron donation to Rh causing a decrease in ?CO due to electron donation into 2π*-CO orbitals. Hydride displacement by CO may occur on exposure to CO(g). The conversion of the species H–Rh(CO)2 to H–Rh(CO) has been followed spectroscopically during desorption.

Bibliography

Yates, J. T., Worley, S. D., Duncan, T. M., & Vaughan, R. W. (1979). Catalytic decomposition of formaldehyde on single rhodium atoms. The Journal of Chemical Physics, 70(3), 1225â1230.

Authors 4

J. T. Yates (first)
S. D. Worley (additional)
T. M. Duncan (additional)
R. W. Vaughan (additional)

References 25 Referenced 49

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{'key': '2024020917315299900_r2', 'first-page': '159', 'volume': '8', 'year': '1973', 'journal-title': 'Catal. Rev. Sci. Eng.'} / Catal. Rev. Sci. Eng. (1973)
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{'key': '2024020917315299900_r6'}
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Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 5:52 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 2:22 p.m.)
Indexed	1 year, 1 month ago (July 20, 2024, 12:10 p.m.)
Issued	46 years, 7 months ago (Feb. 1, 1979)
Published	46 years, 7 months ago (Feb. 1, 1979)
Published Print	46 years, 7 months ago (Feb. 1, 1979)

Funders 0

None

BibTeX

@article{Yates_1979, title={Catalytic decomposition of formaldehyde on single rhodium atoms}, volume={70}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.437604}, DOI={10.1063/1.437604}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Yates, J. T. and Worley, S. D. and Duncan, T. M. and Vaughan, R. W.}, year={1979}, month=feb, pages={1225–1230} }

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