DOI: 10.1063/1.437488. Absolute rate constant for the reaction OH (<i>v</i>=0)+O3→HO2 +O2 over the temperature range 238

Absolute rate constant for the reaction OH (v=0)+O3→HO2 +O2 over the temperature range 238–357 °K

10.1063/1.437488

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The technique of laser flash photolysis–resonance fluorescence has been employed to measure absolute rate constants for the reaction OH (v=0)+O3→HO2+O2 over the temperature range 238–357 K. The results are described by the Arrhenius expression k =1.82+0.35−0.29×10−12 exp[(−930±50)/T] cc/molecule s. Extrapolation of this expression to 225 K, the temperature of the stratosphere in the region where O3 levels are highest, gives a rate constant which is ∼65% higher than the currently recommended value.

Bibliography

Ravishankara, A. R., Wine, P. H., & Langford, A. O. (1979). Absolute rate constant for the reaction OH (v=0)+O3âHO2 +O2 over the temperature range 238â357âÂ°K. The Journal of Chemical Physics, 70(2), 984â989.

Authors 3

A. R. Ravishankara (first)
P. H. Wine (additional)
A. O. Langford (additional)

References 22 Referenced 30

10.1016/0009-2614(73)85131-0 / Chem. Phys. Lett. (1973)
10.1016/0009-2614(73)89003-7 / Chem. Phys. Lett. (1973)
{'key': '2024020917292058900_r3', 'first-page': '273', 'volume': '1', 'year': '1975', 'journal-title': 'Int. J. Chem. Kinet. Symp.'} / Int. J. Chem. Kinet. Symp. (1975)
10.1063/1.1682293 / J. Chem. Phys. (1974)
10.1063/1.1680068 / J. Chem. Phys. (1973)
10.1063/1.1676962 / J. Chem. Phys. (1972)
10.1002/kin.550040402 / Int. J. Chem. Kinet. (1972)
{'key': '2024020917292058900_r8'}
10.1016/0009-2614(72)80296-3 / Chem. Phys. Lett. (1972)
10.1063/1.430882 / J. Chem. Phys. (1975)
10.1063/1.431566 / J. Chem. Phys. (1975)
{'key': '2024020917292058900_r11', 'first-page': '168', 'article-title': 'The Natural Stratosphere of 1974', 'volume': '1', 'year': '1975', 'journal-title': 'CIAP Monogr.'} / CIAP Monogr. / The Natural Stratosphere of 1974 (1975)
10.1063/1.1675031 / J. Chem. Phys. (1971)
10.1063/1.1840747 / J. Chem. Phys. (1967)
10.1063/1.1712297 / J. Chem. Phys. (1967)
10.1364/AO.10.001786 / Appl. Opt. (1971)
10.1063/1.431917 / J. Chem. Phys. (1976)
{'key': '2024020917292058900_r16'}
10.1016/0009-2614(77)80452-1 / Chem. Phys. Lett. (1977)
10.1016/0009-2614(77)80453-3 / Chem. Phys. Lett. (1977)
10.1063/1.434755 / J. Chem. Phys. (1977)
{'key': '2024020917292058900_r20'}

Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 5:52 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 2:19 p.m.)
Indexed	1 year, 5 months ago (March 6, 2024, 6:31 p.m.)
Issued	46 years, 7 months ago (Jan. 15, 1979)
Published	46 years, 7 months ago (Jan. 15, 1979)
Published Print	46 years, 7 months ago (Jan. 15, 1979)

Funders 0

None

BibTeX

@article{Ravishankara_1979, title={Absolute rate constant for the reaction OH (v=0)+O3→HO2 +O2 over the temperature range 238–357 °K}, volume={70}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.437488}, DOI={10.1063/1.437488}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Ravishankara, A. R. and Wine, P. H. and Langford, A. O.}, year={1979}, month=jan, pages={984–989} }

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