DOI: 10.1063/1.436919. Negative ion properties of fluoranil, chloranil, and bromanil: Electron affinities

Negative ion properties of fluoranil, chloranil, and bromanil: Electron affinities

10.1063/1.436919

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Bound and excited negative ion states of p-fluoranil (FA), p-chloranil (CA), and p-bromanil (BA) are studied from experiments involving collisions of electrons, Na, K, and Cs beams with FA, CA, AND BA. Reaction thresholds for producing FA−, CA−, and BA− are determined as a function of the temperature of the target molecules. The electron affinities corresponding to 0 °K were measured to be 2.92±0.2 eV for FA, 2.76±0.2 eV for CA, and 2.44±0.2 eV for BA. FA, CA, and BA attach ∼ 0 eV electrons and FA attaches 0.5 eV electrons to form metastable parent negative ions with lifetimes in the millisecond range. These lifetimes are a function of the electron energy. Dissociative and nondissociative resonances observed via electron attachment to p-benzoquinone (PBQ) and the ’’anils’’ are correlated with the optically determined 2B3g′, 2B1u, and 2Au states of PBQ− and the anion radicals of several substituted quinones.

Bibliography

Cooper, C. D., Frey, W. F., & Compton, R. N. (1978). Negative ion properties of fluoranil, chloranil, and bromanil: Electron affinities. The Journal of Chemical Physics, 69(6), 2367â2374.

Authors 3

C. D. Cooper (first)
W. F. Frey (additional)
R. N. Compton (additional)

References 32 Referenced 50

10.1016/0009-2614(69)80037-0 / Chem. Phys. Lett. (1969)
10.1016/0009-2614(70)80108-7 / Chem. Phys. Lett. (1970)
10.1063/1.431627 / J. Chem. Phys. (1975)
10.1038/196573a0 / Nature (London) (1962)
10.1002/anie.196406171 / Angew. Chem. Int. Ed. Engl. (1964)
10.1063/1.431807 / J. Chem. Phys. (1975)
{'key': '2024020917024852700_r6'}
10.1063/1.1682053 / J. Chem. Phys. (1974)
10.1063/1.1680605 / J. Chem. Phys. (1973)
10.1016/0301-0104(75)87039-X / Chem. Phys. (1975)
10.1063/1.436024 / J. Chem. Phys. (1978)
10.1070/RC1977v046n06ABEH002152 / Russ. Chem. Rev. (1977)
10.1063/1.1680604 / J. Chem. Phys. (1973)
10.1063/1.1726956 / J. Chem. Phys. (1966)
10.1103/PhysRevA.6.631 / Phys. Rev. A (1972)
10.1063/1.1715198 / Rev. Sci. Instrum. (1955)
10.1063/1.1733743 / J. Chem. Phys. (1963)
10.1063/1.1668733 / J. Chem. Phys. (1968)
10.1088/0022-3700/3/7/018 / J. Phys. B (1970)
10.1063/1.1672152 / J. Chem. Phys. (1969)
10.1063/1.1670485 / J. Chem. Phys. (1968)
{'key': '2024020917024852700_r20'}
{'key': '2024020917024852700_r21', 'first-page': '1112', 'volume': '43', 'year': '1969', 'journal-title': 'Russ. J. Phys. Chem.'} / Russ. J. Phys. Chem. (1969)
10.1016/0301-0104(74)80016-9 / Chem. Phys. (1974)
10.1063/1.1667941 / J. Chem. Phys. (1968)
10.1080/00268976400100301 / Mol. Phys. (1964)
10.1246/bcsj.43.2772 / Bull. Chem. Soc. Jpn. (1970)
10.1080/00268976800100851 / Mol. Phys. (1968)
{'key': '2024020917024852700_r26a', 'first-page': 'B', 'volume': '269', 'year': '1969', 'journal-title': 'C. R. Acad. Sc. Paris'} / C. R. Acad. Sc. Paris (1969)
10.1246/bcsj.44.675 / Bull. Chem. Soc. Jpn. (1971)
10.1107/S0365110X62001838 / Acta Cryst. (1962)
10.1063/1.1727547 / J. Chem. Phys. (1966)

Dates

Type	When
Created	22 years, 5 months ago (Feb. 27, 2003, 4:26 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 1:54 p.m.)
Indexed	1 year, 2 months ago (June 6, 2024, 4:36 p.m.)
Issued	46 years, 11 months ago (Sept. 15, 1978)
Published	46 years, 11 months ago (Sept. 15, 1978)
Published Print	46 years, 11 months ago (Sept. 15, 1978)

Funders 0

None

BibTeX

@article{Cooper_1978, title={Negative ion properties of fluoranil, chloranil, and bromanil: Electron affinities}, volume={69}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.436919}, DOI={10.1063/1.436919}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Cooper, C. D. and Frey, W. F. and Compton, R. N.}, year={1978}, month=sep, pages={2367–2374} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        6,
        6
      ]
    ],
    "date-time": "2024-06-06T20:36:56Z",
    "timestamp": 1717706216067
  },
  "reference-count": 32,
  "publisher": "AIP Publishing",
  "issue": "6",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1978,
        9,
        15
      ]
    ]
  },
  "abstract": "<jats:p>Bound and excited negative ion states of p-fluoranil (FA), p-chloranil (CA), and p-bromanil (BA) are studied from experiments involving collisions of electrons, Na, K, and Cs beams with FA, CA, AND BA. Reaction thresholds for producing FA\u2212, CA\u2212, and BA\u2212 are determined as a function of the temperature of the target molecules. The electron affinities corresponding to 0\u2009\u00b0K were measured to be 2.92\u00b10.2 eV for FA, 2.76\u00b10.2 eV for CA, and 2.44\u00b10.2 eV for BA. FA, CA, and BA attach \u223c 0 eV electrons and FA attaches 0.5 eV electrons to form metastable parent negative ions with lifetimes in the millisecond range. These lifetimes are a function of the electron energy. Dissociative and nondissociative resonances observed via electron attachment to p-benzoquinone (PBQ) and the \u2019\u2019anils\u2019\u2019 are correlated with the optically determined 2B3g\u2032, 2B1u, and 2Au states of PBQ\u2212 and the anion radicals of several substituted quinones.</jats:p>",
  "DOI": "10.1063/1.436919",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2003,
        2,
        27
      ]
    ],
    "date-time": "2003-02-27T21:26:05Z",
    "timestamp": 1046381165000
  },
  "page": "2367-2374",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 50,
  "title": "Negative ion properties of fluoranil, chloranil, and bromanil: Electron affinities",
  "prefix": "10.1063",
  "volume": "69",
  "author": [
    {
      "given": "C. D.",
      "family": "Cooper",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Physics, University of Georgia, Athens, Georgia 30602"
        }
      ]
    },
    {
      "given": "W. F.",
      "family": "Frey",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Physics, Davidson College, Davidson, North Carolina 28036"
        }
      ]
    },
    {
      "given": "R. N.",
      "family": "Compton",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Chemical Physics Section, Health and Safety Research Division, Oak Ridge National Laboratory, Oak Ridge, Tenneesee 37830"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020917024852700_r1",
      "doi-asserted-by": "crossref",
      "first-page": "237",
      "DOI": "10.1016/0009-2614(69)80037-0",
      "volume": "3",
      "year": "1969",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020917024852700_r1a",
      "doi-asserted-by": "crossref",
      "first-page": "646",
      "DOI": "10.1016/0009-2614(70)80108-7",
      "volume": "4",
      "year": "1970",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020917024852700_r2",
      "doi-asserted-by": "crossref",
      "first-page": "2752",
      "DOI": "10.1063/1.431627",
      "volume": "63",
      "year": "1975",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r3",
      "doi-asserted-by": "crossref",
      "first-page": "573",
      "DOI": "10.1038/196573a0",
      "volume": "196",
      "year": "1962",
      "journal-title": "Nature (London)"
    },
    {
      "key": "2024020917024852700_r4",
      "doi-asserted-by": "crossref",
      "first-page": "617",
      "DOI": "10.1002/anie.196406171",
      "volume": "3",
      "year": "1964",
      "journal-title": "Angew. Chem. Int. Ed. Engl."
    },
    {
      "key": "2024020917024852700_r5",
      "doi-asserted-by": "crossref",
      "first-page": "3183",
      "DOI": "10.1063/1.431807",
      "volume": "63",
      "year": "1975",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r6"
    },
    {
      "key": "2024020917024852700_r7",
      "doi-asserted-by": "crossref",
      "first-page": "1300",
      "DOI": "10.1063/1.1682053",
      "volume": "61",
      "year": "1974",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r8",
      "doi-asserted-by": "crossref",
      "first-page": "4140",
      "DOI": "10.1063/1.1680605",
      "volume": "59",
      "year": "1973",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r8a",
      "doi-asserted-by": "crossref",
      "first-page": "235",
      "DOI": "10.1016/0301-0104(75)87039-X",
      "volume": "10",
      "year": "1975",
      "journal-title": "Chem. Phys."
    },
    {
      "key": "2024020917024852700_r9",
      "doi-asserted-by": "crossref",
      "first-page": "2023",
      "DOI": "10.1063/1.436024",
      "volume": "68",
      "year": "1978",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r10",
      "doi-asserted-by": "crossref",
      "first-page": "503",
      "DOI": "10.1070/RC1977v046n06ABEH002152",
      "volume": "46",
      "year": "1977",
      "journal-title": "Russ. Chem. Rev."
    },
    {
      "key": "2024020917024852700_r11",
      "doi-asserted-by": "crossref",
      "first-page": "4125",
      "DOI": "10.1063/1.1680604",
      "volume": "59",
      "year": "1973",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r12",
      "doi-asserted-by": "crossref",
      "first-page": "1870",
      "DOI": "10.1063/1.1726956",
      "volume": "44",
      "year": "1966",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r13",
      "doi-asserted-by": "crossref",
      "first-page": "631",
      "DOI": "10.1103/PhysRevA.6.631",
      "volume": "6",
      "year": "1972",
      "journal-title": "Phys. Rev. A"
    },
    {
      "key": "2024020917024852700_r14",
      "doi-asserted-by": "crossref",
      "first-page": "1101",
      "DOI": "10.1063/1.1715198",
      "volume": "26",
      "year": "1955",
      "journal-title": "Rev. Sci. Instrum."
    },
    {
      "key": "2024020917024852700_r15",
      "doi-asserted-by": "crossref",
      "first-page": "780",
      "DOI": "10.1063/1.1733743",
      "volume": "38",
      "year": "1963",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r16",
      "doi-asserted-by": "crossref",
      "first-page": "901",
      "DOI": "10.1063/1.1668733",
      "volume": "48",
      "year": "1968",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r17",
      "doi-asserted-by": "crossref",
      "first-page": "1020",
      "DOI": "10.1088/0022-3700/3/7/018",
      "volume": "3",
      "year": "1970",
      "journal-title": "J. Phys. B"
    },
    {
      "key": "2024020917024852700_r18",
      "doi-asserted-by": "crossref",
      "first-page": "883",
      "DOI": "10.1063/1.1672152",
      "volume": "51",
      "year": "1969",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r19",
      "doi-asserted-by": "crossref",
      "first-page": "2784",
      "DOI": "10.1063/1.1670485",
      "volume": "49",
      "year": "1968",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r20"
    },
    {
      "key": "2024020917024852700_r21",
      "first-page": "1112",
      "volume": "43",
      "year": "1969",
      "journal-title": "Russ. J. Phys. Chem."
    },
    {
      "key": "2024020917024852700_r22",
      "doi-asserted-by": "crossref",
      "first-page": "166",
      "DOI": "10.1016/0301-0104(74)80016-9",
      "volume": "5",
      "year": "1974",
      "journal-title": "Chem. Phys."
    },
    {
      "key": "2024020917024852700_r23",
      "doi-asserted-by": "crossref",
      "first-page": "440",
      "DOI": "10.1063/1.1667941",
      "volume": "48",
      "year": "1968",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020917024852700_r24",
      "doi-asserted-by": "crossref",
      "first-page": "265",
      "DOI": "10.1080/00268976400100301",
      "volume": "8",
      "year": "1964",
      "journal-title": "Mol. Phys."
    },
    {
      "key": "2024020917024852700_r25",
      "doi-asserted-by": "crossref",
      "first-page": "2772",
      "DOI": "10.1246/bcsj.43.2772",
      "volume": "43",
      "year": "1970",
      "journal-title": "Bull. Chem. Soc. Jpn."
    },
    {
      "key": "2024020917024852700_r26",
      "doi-asserted-by": "crossref",
      "first-page": "97",
      "DOI": "10.1080/00268976800100851",
      "volume": "15",
      "year": "1968",
      "journal-title": "Mol. Phys."
    },
    {
      "key": "2024020917024852700_r26a",
      "first-page": "B",
      "volume": "269",
      "year": "1969",
      "journal-title": "C. R. Acad. Sc. Paris"
    },
    {
      "key": "2024020917024852700_r27",
      "doi-asserted-by": "crossref",
      "first-page": "675",
      "DOI": "10.1246/bcsj.44.675",
      "volume": "44",
      "year": "1971",
      "journal-title": "Bull. Chem. Soc. Jpn."
    },
    {
      "key": "2024020917024852700_r28",
      "doi-asserted-by": "crossref",
      "first-page": "661",
      "DOI": "10.1107/S0365110X62001838",
      "volume": "15",
      "year": "1962",
      "journal-title": "Acta Cryst."
    },
    {
      "key": "2024020917024852700_r29",
      "doi-asserted-by": "crossref",
      "first-page": "4634",
      "DOI": "10.1063/1.1727547",
      "volume": "45",
      "year": "1966",
      "journal-title": "J. Chem. Phys."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/69/6/2367/18913705/2367_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/69/6/2367/18913705/2367_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T18:54:18Z",
    "timestamp": 1707504858000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/69/6/2367/86505/Negative-ion-properties-of-fluoranil-chloranil-and"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1978,
        9,
        15
      ]
    ]
  },
  "references-count": 32,
  "journal-issue": {
    "issue": "6",
    "published-print": {
      "date-parts": [
        [
          1978,
          9,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.436919",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1978,
        9,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1978,
        9,
        15
      ]
    ]
  }
}