DOI: 10.1063/1.436796. Uniform theory of electron kinetics in nonpolar liquids

Uniform theory of electron kinetics in nonpolar liquids

10.1063/1.436796

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Application of the Smoluchowski–Debye equation results in a uniform treatment of the kinetics of either of the bulk reactions e− +M+→M or e−+A→A−, and the corresponding photoionization reaction, either M⇄hνM++e− or A−⇄hνA+e−. For simplicity of terminology, the bulk reactions are referred to as class I and the photoionizations as class II. Included in the theory are the following effects: (1) solvent screening of the interaction potential between e− and either of the acceptors M+ or A, (2) spatial variation of electron transport coefficients (mobility and diffusion tensor) due to the internal electric field associated with the interaction potential, (3) electron tunneling, and (4) chemical activation processes. By use of Green’s function methods, we arrive at the result n1(r)exp[−ψ (r)]=NsP (r), where n1(r) is the pair density at a relative separation r in a reaction of class I, and P (r) is the escape probability for a pair initially at a separation r in the corresponding reaction of class II. The quantity Ns is the electron concentration in the class I reaction (Ns=NM+ or NA).

Bibliography

Rice, S. A., & Baird, J. K. (1978). Uniform theory of electron kinetics in nonpolar liquids. The Journal of Chemical Physics, 69(5), 1989â1995.

Authors 2

Stephen A. Rice (first)
James K. Baird (additional)

References 39 Referenced 16

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{'key': '2024020917050480600_r25'}

Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 4:26 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 1:55 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 6:45 a.m.)
Issued	47 years ago (Sept. 1, 1978)
Published	47 years ago (Sept. 1, 1978)
Published Print	47 years ago (Sept. 1, 1978)

Funders 0

None

BibTeX

@article{Rice_1978, title={Uniform theory of electron kinetics in nonpolar liquids}, volume={69}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.436796}, DOI={10.1063/1.436796}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Rice, Stephen A. and Baird, James K.}, year={1978}, month=sep, pages={1989–1995} }

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