DOI: 10.1063/1.436352. Semiclassical theory of collision-induced vibration–rotational transitions. Application to methylhalides

Semiclassical theory of collision-induced vibration–rotational transitions. Application to methylhalides

10.1063/1.436352

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A theory of collision-induced vibrational transitions in polyatomic molecules is presented in which the effects of molecular rotation are included. Translations are treated classically and the molecule itself is considered as classical top with internal degrees of freedom, i.e., normal mode vibrations, treated quantum mechanically. The theory is successfully applied to interpret the behavior of the vibrational relaxation rates of methylhalides upon the mass of the collision partner.

Bibliography

Miklavc, A., & Fischer, S. (1978). Semiclassical theory of collision-induced vibrationârotational transitions. Application to methylhalides. The Journal of Chemical Physics, 69(1), 281â287.

Authors 2

Adolf Miklavc (first)
Sighart Fischer (additional)

References 54 Referenced 72

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Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 4:26 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 1:51 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 10:21 a.m.)
Issued	47 years, 2 months ago (July 1, 1978)
Published	47 years, 2 months ago (July 1, 1978)
Published Print	47 years, 2 months ago (July 1, 1978)

Funders 0

None

BibTeX

@article{Miklavc_1978, title={Semiclassical theory of collision-induced vibration–rotational transitions. Application to methylhalides}, volume={69}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.436352}, DOI={10.1063/1.436352}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Miklavc, Adolf and Fischer, Sighart}, year={1978}, month=jul, pages={281–287} }

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    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1978,
        7,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1978,
        7,
        1
      ]
    ]
  }
}