DOI: 10.1063/1.435916. Optimized Rouse–Zimm theory for stiff polymers

Optimized Rouse–Zimm theory for stiff polymers

10.1063/1.435916

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Earlier, the authors proposed a method for constructing an optimized Rouse–Zimm theory for an arbitrary polymer system. This method is applied here to a model of a stiff polymer. The spectrum of relaxation times and the intrinsic viscosity obtained from the optimized Rouse–Zimm theory are discussed. Comparison with known results for the limiting cases of a flexible chain, a rigid ring, and a rigid rod, shows that this procedure gives a quite good approximation at low frequencies. Its basic disadvantage is its inability to account for the observed high frequency behavior of the intrinsic viscosity of stiff polymers.

Bibliography

Bixon, M., & Zwanzig, R. (1978). Optimized RouseâZimm theory for stiff polymers. The Journal of Chemical Physics, 68(4), 1896â1902.

Authors 2

Mordechai Bixon (first)
Robert Zwanzig (additional)

References 14 Referenced 135

10.1063/1.1679380 / J. Chem. Phys. (1973)
10.1063/1.1681433 / J. Chem. Phys. (1974)
10.1063/1.1699180 / J. Chem. Phys. (1953)
10.1063/1.1742462 / J. Chem. Phys. (1956)
10.1063/1.1727098 / J. Chem. Phys. (1966)
10.1063/1.1728067 / J. Chem. Phys. (1966)
10.1063/1.1672109 / J. Chem. Phys. (1969)
{'key': '2024020916403463000_r7'}
{'key': '2024020916403463000_r8'}
10.1063/1.1733300 / J. Chem. Phys. (1962)
10.1063/1.431352 / J. Chem. Phys. (1975)
10.1063/1.433869 / J. Chem. Phys. (1977)
{'key': '2024020916403463000_r11a'}
10.1063/1.1681833 / J. Chem. Phys. (1974)

Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 5:38 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 1:34 p.m.)
Indexed	1 year, 1 month ago (July 26, 2024, 9:59 a.m.)
Issued	47 years, 6 months ago (Feb. 15, 1978)
Published	47 years, 6 months ago (Feb. 15, 1978)
Published Print	47 years, 6 months ago (Feb. 15, 1978)

Funders 0

None

BibTeX

@article{Bixon_1978, title={Optimized Rouse–Zimm theory for stiff polymers}, volume={68}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.435916}, DOI={10.1063/1.435916}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Bixon, Mordechai and Zwanzig, Robert}, year={1978}, month=feb, pages={1896–1902} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        7,
        26
      ]
    ],
    "date-time": "2024-07-26T13:59:16Z",
    "timestamp": 1722002356218
  },
  "reference-count": 14,
  "publisher": "AIP Publishing",
  "issue": "4",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1978,
        2,
        15
      ]
    ]
  },
  "abstract": "<jats:p>Earlier, the authors proposed a method for constructing an optimized Rouse\u2013Zimm theory for an arbitrary polymer system. This method is applied here to a model of a stiff polymer. The spectrum of relaxation times and the intrinsic viscosity obtained from the optimized Rouse\u2013Zimm theory are discussed. Comparison with known results for the limiting cases of a flexible chain, a rigid ring, and a rigid rod, shows that this procedure gives a quite good approximation at low frequencies. Its basic disadvantage is its inability to account for the observed high frequency behavior of the intrinsic viscosity of stiff polymers.</jats:p>",
  "DOI": "10.1063/1.435916",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2003,
        2,
        27
      ]
    ],
    "date-time": "2003-02-27T22:38:05Z",
    "timestamp": 1046385485000
  },
  "page": "1896-1902",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 135,
  "title": "Optimized Rouse\u2013Zimm theory for stiff polymers",
  "prefix": "10.1063",
  "volume": "68",
  "author": [
    {
      "given": "Mordechai",
      "family": "Bixon",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742"
        }
      ]
    },
    {
      "given": "Robert",
      "family": "Zwanzig",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020916403463000_r1",
      "doi-asserted-by": "crossref",
      "first-page": "1459",
      "DOI": "10.1063/1.1679380",
      "volume": "58",
      "year": "1973",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020916403463000_r2",
      "doi-asserted-by": "crossref",
      "first-page": "2717",
      "DOI": "10.1063/1.1681433",
      "volume": "60",
      "year": "1974",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020916403463000_r3",
      "doi-asserted-by": "crossref",
      "first-page": "1272",
      "DOI": "10.1063/1.1699180",
      "volume": "21",
      "year": "1953",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020916403463000_r4",
      "doi-asserted-by": "crossref",
      "first-page": "269",
      "DOI": "10.1063/1.1742462",
      "volume": "24",
      "year": "1956",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020916403463000_r5",
      "doi-asserted-by": "crossref",
      "first-page": "2595",
      "DOI": "10.1063/1.1727098",
      "volume": "44",
      "year": "1966",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020916403463000_r5a",
      "doi-asserted-by": "crossref",
      "first-page": "3106",
      "DOI": "10.1063/1.1728067",
      "volume": "45",
      "year": "1966",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020916403463000_r6",
      "doi-asserted-by": "crossref",
      "first-page": "1102",
      "DOI": "10.1063/1.1672109",
      "volume": "51",
      "year": "1969",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020916403463000_r7"
    },
    {
      "key": "2024020916403463000_r8"
    },
    {
      "key": "2024020916403463000_r9",
      "doi-asserted-by": "crossref",
      "first-page": "1425",
      "DOI": "10.1063/1.1733300",
      "volume": "37",
      "year": "1962",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020916403463000_r10",
      "doi-asserted-by": "crossref",
      "first-page": "740",
      "DOI": "10.1063/1.431352",
      "volume": "63",
      "year": "1975",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020916403463000_r11",
      "doi-asserted-by": "crossref",
      "first-page": "5500",
      "DOI": "10.1063/1.433869",
      "volume": "66",
      "year": "1977",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020916403463000_r11a"
    },
    {
      "key": "2024020916403463000_r11b",
      "doi-asserted-by": "crossref",
      "first-page": "4939",
      "DOI": "10.1063/1.1681833",
      "volume": "61",
      "year": "1974",
      "journal-title": "J. Chem. Phys."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/68/4/1896/18911689/1896_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/68/4/1896/18911689/1896_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T18:34:39Z",
    "timestamp": 1707503679000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/68/4/1896/800025/Optimized-Rouse-Zimm-theory-for-stiff-polymers"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1978,
        2,
        15
      ]
    ]
  },
  "references-count": 14,
  "journal-issue": {
    "issue": "4",
    "published-print": {
      "date-parts": [
        [
          1978,
          2,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.435916",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1978,
        2,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1978,
        2,
        15
      ]
    ]
  }
}