DOI: 10.1063/1.435651. The selective dissociation of SF6 in an intense ir field: A molecular beam study on the influence of laser wavelength and energy

The selective dissociation of SF6 in an intense ir field: A molecular beam study on the influence of laser wavelength and energy

10.1063/1.435651

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We report the results of a molecular beam study on the energy fluence and wavelength dependence of the dissociation probability of SF6. We find surprisingly high values at power densities which rule out an essential contribution of power broadening but rather stress the importance of efficient absorption in the lower levels. No loss of isotopic selectivity is observed for power densities up to 108 W/cm2 in the P (20) line at 944.2 cm−1.

Bibliography

Brunner, F., & Proch, D. (1978). The selective dissociation of SF6 in an intense ir field: A molecular beam study on the influence of laser wavelength and energy. The Journal of Chemical Physics, 68(11), 4936â4940.

Authors 2

F. Brunner (first)
D. Proch (additional)

References 27 Referenced 42

10.1021/ar50110a005 / Acc. Chem. Res. (1977)
10.1070/QE1976v006n03ABEH010990 / Sov. J. Quantum Electron. (1976)
{'key': '2024020916414241700_r3'}
10.1016/0030-4018(76)90252-2 / Opt. Commun. (1976)
10.1016/0030-4018(76)90253-4 / Opt. Commun. (1976)
10.1016/0030-4018(76)90308-4 / Opt. Commun. (1976)
10.1016/0030-4018(76)90309-6 / Opt. Commun. (1976)
10.1063/1.434984 / J. Chem. Phys. (1977)
{'key': '2024020916414241700_r8'}
10.1016/0022-2852(75)90164-2 / J. Mol. Spectrosc. (1975)
10.1021/j100552a017 / J. Phys. Chem. (1976)
{'key': '2024020916414241700_r11'}
10.1063/1.1671638 / J. Chem. Phys. (1969)
10.1063/1.1672089 / J. Chem. Phys. (1969)
10.1063/1.1682537 / J. Chem. Phys. (1974)
10.1016/0022-4073(75)90138-7 / J. Quant. Spectrosc. Radiat. Transfer (1975)
{'key': '2024020916414241700_r16'}
{'key': '2024020916414241700_r17'}
{'key': '2024020916414241700_r18'}
10.1016/0030-4018(77)90176-6 / Opt. Commun. (1977)
10.1016/0009-2614(77)85245-7 / Chem. Phys. Lett. (1977)
10.1016/0009-2614(76)80597-0 / Chem. Phys. Lett. (1976)
10.1088/0022-3700/10/13/013 / J. Phys. B: (1977)
10.1016/0030-4018(77)90175-4 / Opt. Commun. (1977)
10.1016/0009-2614(76)80628-8 / Chem. Phys. Lett. (1976)
10.1007/BF00915201 / Appl. Phys. (1977)
10.1063/1.435117 / J. Chem. Phys. (1977)

Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 5:38 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 1:37 p.m.)
Indexed	3 months, 2 weeks ago (May 19, 2025, 7:26 a.m.)
Issued	47 years, 3 months ago (June 1, 1978)
Published	47 years, 3 months ago (June 1, 1978)
Published Print	47 years, 3 months ago (June 1, 1978)

Funders 0

None

BibTeX

@article{Brunner_1978, title={The selective dissociation of SF6 in an intense ir field: A molecular beam study on the influence of laser wavelength and energy}, volume={68}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.435651}, DOI={10.1063/1.435651}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Brunner, F. and Proch, D.}, year={1978}, month=jun, pages={4936–4940} }

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