DOI: 10.1063/1.435507. On the theory of chemically induced electron polarization (CIDEP): Vector model and an asymptotic solution

On the theory of chemically induced electron polarization (CIDEP): Vector model and an asymptotic solution

10.1063/1.435507

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

It is shown that the stochastic–Liouville model of CIDEP can be cast into the form of a ’’Bloch-type’’ equation with diffusion. This leads to a generalized vector model of the radical pair mechanism of chemically induced magnetic polarization, which gives a clear picture of the qualitative features of both CIDNP and CIDEP. For the case of simple Brownian motion of the two radicals the differential form of the stochastic–Liouville equations of CIDEP is readily converted into a single integral equation. In the limit of slow singlet–triplet mixing by the magnetic spin Hamiltonian, and with an exchange interaction that decays exponentially with radical separation, this integral equation may be solved exactly. The electron polarization then takes the form of a superposition of an infinite number of ’’contact exchange modes’’.

Bibliography

Monchick, L., & Adrian, F. J. (1978). On the theory of chemically induced electron polarization (CIDEP): Vector model and an asymptotic solution. The Journal of Chemical Physics, 68(10), 4376â4383.

Authors 2

L. Monchick (first)
F. J. Adrian (additional)

References 31 Referenced 92

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Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 5:38 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 1:18 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 11:04 a.m.)
Issued	47 years, 3 months ago (May 15, 1978)
Published	47 years, 3 months ago (May 15, 1978)
Published Print	47 years, 3 months ago (May 15, 1978)

Funders 0

None

BibTeX

@article{Monchick_1978, title={On the theory of chemically induced electron polarization (CIDEP): Vector model and an asymptotic solution}, volume={68}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.435507}, DOI={10.1063/1.435507}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Monchick, L. and Adrian, F. J.}, year={1978}, month=may, pages={4376–4383} }

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