Absolute rate constants for the reaction of OH radicals with allene, 1,3-butadiene, and 3-methyl-1-butene over the temperature range 299–424 °K
10.1063/1.435230
Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

Absolute rate constants for the reaction of OH radicals with allene, 1,3-butadiene, and 3-methyl-l-butene have been determined over the temperature range 299–424 °K, using a flash photolysis–resonance fluorescence technique. The Arrhenius expressions obtained were k (allene) =5.59×10−12 e(305±300)/RT cm3 molecule−1 sec−1, k (1,3-butadiene) =1.45×10−11 e(930±300)/RT cm3 molecule−1 sec−1, k (3-methyl-1-butene) =5.23×10−12 e(1060±300)/RT cm3 molecule−1 sec −1, with rate constants at room temperature of (9.30±0.93) ×10−12, (6.85±0.69) ×10−11, and (3.10±0.31) ×10−11 cm3 molecule−1 sec−1 for allene, 1,3-butadiene, and 3-methyl-l-butene, respectively.

Bibliography

Atkinson, R., Perry, R. A., & Pitts, J. N. (1977). Absolute rate constants for the reaction of OH radicals with allene, 1,3-butadiene, and 3-methyl-1-butene over the temperature range 299–424 °K. The Journal of Chemical Physics, 67(7), 3170–3174.

Authors 3
  1. R. Atkinson (first)
  2. R. A. Perry (additional)
  3. J. N. Pitts (additional)
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Dates
Type When
Created 22 years, 6 months ago (Feb. 12, 2003, 4:34 p.m.)
Deposited 1 year, 6 months ago (Feb. 9, 2024, 11:53 a.m.)
Indexed 1 year, 1 month ago (July 5, 2024, 12:01 p.m.)
Issued 47 years, 11 months ago (Oct. 1, 1977)
Published 47 years, 11 months ago (Oct. 1, 1977)
Published Print 47 years, 11 months ago (Oct. 1, 1977)
Funders 0

None

@article{Atkinson_1977, title={Absolute rate constants for the reaction of OH radicals with allene, 1,3-butadiene, and 3-methyl-1-butene over the temperature range 299–424 °K}, volume={67}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.435230}, DOI={10.1063/1.435230}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Atkinson, R. and Perry, R. A. and Pitts, J. N.}, year={1977}, month=oct, pages={3170–3174} }