DOI: 10.1063/1.434904. Isostructural phase transitions due to core collapse. III. A model for solid mixtures

Isostructural phase transitions due to core collapse. III. A model for solid mixtures

10.1063/1.434904

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Our earlier development of a statistical mechanical theory of isostructural phase transitions due to core collapse [J. Chem. Phys. 65, 2161, 2172 (1976)] is extended to the treatment of solid mixtures exhibiting isostructural transitions. Since mixtures in which two solid phases coexist are typically in states of mechanical but not material equilibrium, we consider the theory for states of mechanical equilibrium only, as well as the theory for coexisting phases in true stable thermodynamic equilibrium. Using an extremely simple Hamiltonian model we find good qualitative agreement between the results of a first-order perturbation theory and the recent experimental results for Ce1−xThx mixtures. In particular, the theory accounts for the experimentally observed decrease in critical temperature with increasing x and for the dependence of the observed resistivity–temperature isobars upon x.

Authors 2

J. M. Kincaid (first)
G. Stell (additional)

References 38 Referenced 34

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10.1002/bbpc.19720760330 / Ber. Bunsenges. Phys. Chem. (1972)
10.1021/cr60294a001 / Chem. Rev. (1975)
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{'key': '2024020915263573700_r8a', 'first-page': '1649', 'volume': '30', 'year': '1976', 'journal-title': 'Mol. Phys.'} / Mol. Phys. (1976)
10.1016/0022-3697(60)90247-X / J. Phys. Chem. Solids (1960)
10.1016/0022-3697(64)90003-4 / J. Phys. Chem. Solids (1964)
10.1103/PhysRev.137.A179 / Phys. Rev. Sect. A (1965)
{'key': '2024020915263573700_r9c', 'first-page': '3229', 'volume': '9', 'year': '1975', 'journal-title': 'Phys. Rev. B'} / Phys. Rev. B (1975)
10.1103/PhysRevB.11.2783 / Phys. Rev. B (1975)
10.1016/0022-3697(62)90513-9 / J. Phys. Chem. Solids (1962)
{'key': '2024020915263573700_r10a', 'first-page': '301', 'volume': '2', 'year': '1966', 'journal-title': 'J. Less-Common Met.'} / J. Less-Common Met. (1966)
10.1103/PhysRevLett.35.289 / Phys. Rev. Lett. (1975)
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10.1143/PTP.47.1069 / Prog. Theor. Phys. (1972)
{'key': '2024020915263573700_r22'}
{'key': '2024020915263573700_r23'}
10.1016/0375-9601(76)90487-4 / Phys. Lett. A (1976)
{'key': '2024020915263573700_r25'}
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10.1063/1.1670653 / J. Chem. Phys. (1968)

Dates

Type	When
Created	22 years, 6 months ago (Feb. 12, 2003, 4:34 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 11:16 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 2:28 p.m.)
Issued	48 years, 1 month ago (July 15, 1977)
Published	48 years, 1 month ago (July 15, 1977)
Published Print	48 years, 1 month ago (July 15, 1977)

Funders 0

None

BibTeX

@article{Kincaid_1977, title={Isostructural phase transitions due to core collapse. III. A model for solid mixtures}, volume={67}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.434904}, DOI={10.1063/1.434904}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Kincaid, J. M. and Stell, G.}, year={1977}, month=jul, pages={420–429} }

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