DOI: 10.1063/1.434619. The effects of hydrodynamic interactions on translational and rotational relaxation

The effects of hydrodynamic interactions on translational and rotational relaxation

10.1063/1.434619

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A theory of coupled translational and rotational relaxation in solution including the effects of hydrodynamic interaction is presented. The translational, translational–rotational, and rotational diffusion tensors are computed using the method of hydrodynamic reflections. The correlation functions Clm(t) =〈Ylm*[u(0)] Ylm[u(t)]〉 and Clm(q,t) =〈exp iq⋅[r(t)−r(0)] Ylm*[u(0)] Ylm[u(t)]〉 are found from a coupled translational–rotational diffusion equation. Clm(t) is shown to reduce to the Debye result under conditions relevant to magnetic resonance experiments. The concentration dependence of the rotational diffusion coefficient is calculated and compared with experiment. The failure of the results to account for the dynamical correlations seen in recent NMR studies of protein solutions by Koenig and co-workers is discussed.

Bibliography

Montgomery, J. A., & Berne, B. J. (1977). The effects of hydrodynamic interactions on translational and rotational relaxation. The Journal of Chemical Physics, 67(10), 4589â4596.

Authors 2

John A. Montgomery (first)
Bruce J. Berne (additional)

References 28 Referenced 42

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Dates

Type	When
Created	22 years, 6 months ago (Feb. 12, 2003, 4:34 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 11:56 a.m.)
Indexed	1 year ago (Aug. 12, 2024, 9:18 a.m.)
Issued	47 years, 9 months ago (Nov. 15, 1977)
Published	47 years, 9 months ago (Nov. 15, 1977)
Published Print	47 years, 9 months ago (Nov. 15, 1977)

Funders 0

None

BibTeX

@article{Montgomery_1977, title={The effects of hydrodynamic interactions on translational and rotational relaxation}, volume={67}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.434619}, DOI={10.1063/1.434619}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Montgomery, John A. and Berne, Bruce J.}, year={1977}, month=nov, pages={4589–4596} }

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