DOI: 10.1063/1.434577. Quantum-dynamical model for thermal desorption of gases from solid surfaces

Quantum-dynamical model for thermal desorption of gases from solid surfaces

10.1063/1.434577

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The Montroll–Shuler model for the kinetics of dissociation of a diatomic molecule in a heat bath is adapted to thermal desorption of gases from solid surfaces. The rate constant kMS is compared with that predicted by transition-state theory, kTST, and that extracted from experimental data for the system Xe/W. A central feature of the present model is that kMS shows a strong explicit dependence (ϑ−3D in the Debye approximation) upon the lattice dynamics, whereas kTST has none at all.

Bibliography

Garrison, B. J., Diestler, D. J., & Adelman, S. A. (1977). Quantum-dynamical model for thermal desorption of gases from solid surfaces. The Journal of Chemical Physics, 67(10), 4317â4320.

Authors 3

B. J. Garrison (first)
D. J. Diestler (additional)
S. A. Adelman (additional)

References 26 Referenced 28

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10.1063/1.432526 / J. Chem. Phys. (1976)
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10.1063/1.433565 / J. Chem. Phys. (1976)
10.1016/0039-6028(77)90411-3 / Surf. Sci. (1977)
10.1063/1.434249 / J. Chem. Phys. (1977)
10.1063/1.435077 / J. Chem. Phys. (1977)
{'key': '2024020915565233400_r7'}
10.1021/j150489a013 / J. Phys. Colloid Chem. (1951)
10.1063/1.1700424 / J. Chem. Phys. (1952)
10.1098/rspa.1935.0114 / Proc. R. Soc. London Ser. A (1935)
10.1098/rspa.1935.0115 / Proc. R. Soc. London Ser. A (1935)
10.1098/rspa.1936.0131 / Proc. R. Soc. London Ser. A (1936)
10.1103/PhysRevB.7.622 / Phys. Rev. B (1973)
10.1103/PhysRevB.7.637 / Phys. Rev. B (1973)
{'key': '2024020915565233400_r12', 'first-page': '361', 'volume': '1', 'year': '1958', 'journal-title': 'Adv. Chem. Phys.'} / Adv. Chem. Phys. (1958)
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{'key': '2024020915565233400_r15'}
{'key': '2024020915565233400_r16'}
10.1016/S0031-8914(40)90098-2 / Physica (Utrecht) (1940)
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{'key': '2024020915565233400_r18'}

Dates

Type	When
Created	22 years, 6 months ago (Feb. 12, 2003, 4:34 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 11:57 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 9:59 a.m.)
Issued	47 years, 9 months ago (Nov. 15, 1977)
Published	47 years, 9 months ago (Nov. 15, 1977)
Published Print	47 years, 9 months ago (Nov. 15, 1977)

Funders 0

None

BibTeX

@article{Garrison_1977, title={Quantum-dynamical model for thermal desorption of gases from solid surfaces}, volume={67}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.434577}, DOI={10.1063/1.434577}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Garrison, B. J. and Diestler, D. J. and Adelman, S. A.}, year={1977}, month=nov, pages={4317–4320} }

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