DOI: 10.1063/1.433987. Statistical–mechanical theory of gaseous ion–molecule reactions in an electrostatic field

Statistical–mechanical theory of gaseous ion–molecule reactions in an electrostatic field

10.1063/1.433987

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A theory is developed for gas-phase swarm measurements of ion–molecule reactions in electrostatic fields of arbitrary strength. The theory allows measurements of reaction rate coefficients made at low temperatures and strong electric fields to be converted directly to equivalent thermal rate coefficients at elevated temperatures inaccessible by direct methods. It is not necessary to calculate the ion velocity distribution function explicitly, or to unfold the reaction cross section from the rate data. In first approximation the measured rate coefficient is equal to the thermal rate coefficient at an effective temperature calculated directly from the measured ion drift velocity. Higher approximations are obtained from more detailed analysis of the dependence of the rate coefficient and drift velocity on electric field strength. Comparison is made with experimental data reported in an accompanying paper by Albritton et al. In another accompanying paper, Lin and Bardsley compare the present theory with their detailed Monte Carlo calculations.

Bibliography

Viehland, L. A., & Mason, E. A. (1977). Statisticalâmechanical theory of gaseous ionâmolecule reactions in an electrostatic field. The Journal of Chemical Physics, 66(2), 422â434.

Authors 2

Larry A. Viehland (first)
E. A. Mason (additional)

References 40 Referenced 102

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Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 5:23 p.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 5:58 p.m.)
Indexed	1 year, 1 month ago (July 26, 2024, 4:26 a.m.)
Issued	48 years, 7 months ago (Jan. 15, 1977)
Published	48 years, 7 months ago (Jan. 15, 1977)
Published Print	48 years, 7 months ago (Jan. 15, 1977)

Funders 0

None

BibTeX

@article{Viehland_1977, title={Statistical–mechanical theory of gaseous ion–molecule reactions in an electrostatic field}, volume={66}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.433987}, DOI={10.1063/1.433987}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Viehland, Larry A. and Mason, E. A.}, year={1977}, month=jan, pages={422–434} }

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