DOI: 10.1063/1.433651. A study of hydrogen bonding in methanol vapor by measurement of thermal conductivity

A study of hydrogen bonding in methanol vapor by measurement of thermal conductivity

10.1063/1.433651

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The thermal conductivity of methanol vapor was measured in a modified thick hot-wire cell between 307 and 345 K at pressures ranging from approximately 50 torr up to a maximum of 1 atm. Analysis of the experimental data indicates that a tetrameric species is the principal source of the observed enhancement of the thermal conductivity of the vapor due to association reactions. Equilibrium constants for the reaction 4CH3OH? (CH3OH)4 were determined from the thermal conductivity data. The enthalpy of formation of the methanol tetramer is −23.73 kcal/mole and the entropy of formation is −80.92 cal/mole K.

Bibliography

Renner, T. A., Kucera, G. H., & Blander, M. (1977). A study of hydrogen bonding in methanol vapor by measurement of thermal conductivity. The Journal of Chemical Physics, 66(1), 177â184.

Authors 3

T. A. Renner (first)
G. H. Kucera (additional)
M. Blander (additional)

References 44 Referenced 62

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Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 5:23 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 10:46 a.m.)
Indexed	1 year, 1 month ago (July 1, 2024, 1:54 a.m.)
Issued	48 years, 7 months ago (Jan. 1, 1977)
Published	48 years, 7 months ago (Jan. 1, 1977)
Published Print	48 years, 7 months ago (Jan. 1, 1977)

Funders 0

None

BibTeX

@article{Renner_1977, title={A study of hydrogen bonding in methanol vapor by measurement of thermal conductivity}, volume={66}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.433651}, DOI={10.1063/1.433651}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Renner, T. A. and Kucera, G. H. and Blander, M.}, year={1977}, month=jan, pages={177–184} }

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