DOI: 10.1063/1.432731. An NMR study of the alkali metal intercalation phase Li<i>x</i>TiS2: Relation to structure, thermodynamics, and ionicity

An NMR study of the alkali metal intercalation phase LixTiS2: Relation to structure, thermodynamics, and ionicity

10.1063/1.432731

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The Knight shift and electric quadrupole coupling constant have been measured as a function of lithium concentration in the continuous intercalation phase LixTiS2 where 0⩽x⩽1. These NMR data, when compared with observations of c axis dilation and thermodynamics of this phase, suggest the donation of an appreciable fraction of the Li 2s electron to the TiS2 layers during intercalation, with the fraction diminishing as x increases. The relation of the charge donated to each of the observed quantities is discussed.

Bibliography

Silbernagel, B. G., & Whittingham, M. S. (1976). An NMR study of the alkali metal intercalation phase LixTiS2: Relation to structure, thermodynamics, and ionicity. The Journal of Chemical Physics, 64(9), 3670â3673.

Authors 2

B. G. Silbernagel (first)
M. S. Whittingham (additional)

References 16 Referenced 93

{'key': '2024020914083696000_r1'}
10.1016/0025-5408(75)90115-4 / Mat. Res. Bull. (1975)
10.1016/0025-5408(75)90006-9 / Mat. Res. Bull. (1975)
10.1016/0038-1098(75)90312-9 / Solid State Commun. (1975)
{'key': '2024020914083696000_r5'}
10.1149/1.2132817 / J. Electrochem. Soc. (1976)
10.1016/0025-5408(75)90071-9 / Mat. Res. Bull. (1975)
{'key': '2024020914083696000_r7', 'first-page': '1283', 'volume': '276', 'year': '1973', 'journal-title': 'C. R. Acad. Sci. Ser. C'} / C. R. Acad. Sci. Ser. C (1973)
{'key': '2024020914083696000_r8'}
10.1063/1.1700782 / J. Chem. Phys. (1952)
{'key': '2024020914083696000_r10'}
10.1103/PhysRev.133.B270 / Phys. Rev. B (1964)
10.1016/0025-5408(76)90210-5 / Mat. Res. Bull. (1976)
{'key': '2024020914083696000_r13'}
10.1103/PhysRev.101.58 / Phys. Rev. (1956)
{'key': '2024020914083696000_r15', 'first-page': '2284', 'volume': '2', 'year': '1970', 'journal-title': 'Phys. Rev. B'} / Phys. Rev. B (1970)

Dates

Type	When
Created	22 years, 5 months ago (Feb. 27, 2003, 5:10 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 9:53 a.m.)
Indexed	1 year ago (July 31, 2024, 8:29 a.m.)
Issued	49 years, 3 months ago (May 1, 1976)
Published	49 years, 3 months ago (May 1, 1976)
Published Print	49 years, 3 months ago (May 1, 1976)

Funders 0

None

BibTeX

@article{Silbernagel_1976, title={An NMR study of the alkali metal intercalation phase LixTiS2: Relation to structure, thermodynamics, and ionicity}, volume={64}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.432731}, DOI={10.1063/1.432731}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Silbernagel, B. G. and Whittingham, M. S.}, year={1976}, month=may, pages={3670–3673} }

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