DOI: 10.1063/1.432727. Outer-sphere electron-transfer reactions in polar solvents

Outer-sphere electron-transfer reactions in polar solvents

10.1063/1.432727

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A model for outer-sphere electron-transfer reactions in polar solutions is suggested. It is based on the idea of dividing the system into two subsystems, a classical solvent and quantum mechanical interacting molecules. The solvent is looked upon as the source of an external field and is coupled parametrically to the reacting species. The model is analytically solved, under some approximations, for the transfer probability. Using a specific macroscopic model of the solvent a usable expression for the rate constant is given. Operational and physical criteria are developed regarding the problems of adiabaticity, nonadiabaticity, and independence on the solvent dynamics.

Bibliography

Efrima, S., & Bixon, M. (1976). Outer-sphere electron-transfer reactions in polar solvents. The Journal of Chemical Physics, 64(9), 3639â3647.

Authors 2

Shlomo Efrima (first)
Mordechai Bixon (additional)

References 13 Referenced 39

10.1063/1.1742723 / J. Chem. Phys. (1956)
10.1063/1.1742724 / J. Chem. Phys. (1956)
10.1146/annurev.pc.15.100164.001103 / Ann. Rev. Phys. Chem. (1964)
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{'key': '2024020914103583300_r4a'}
10.1016/S0022-0728(71)80189-4 / J. Electroanal. Chem. (1971)
10.1063/1.1677607 / J. Chem. Phys. (1972)
10.1063/1.1678998 / J. Chem. Phys. (1973)
10.1098/rspa.1932.0165 / Proc. R. Soc. London Ser. A (1932)
10.1021/j100614a017 / J. Phys. Chem. (1974)
10.1063/1.1734514 / J. Chem. Phys. (1963)
10.1002/ijch.197000029 / Israel J. Chem. (1970)
10.1016/0009-2614(74)80325-8 / Chem. Phys. Lett. (1974)

Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 5:10 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 9:55 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 3:20 a.m.)
Issued	49 years, 3 months ago (May 1, 1976)
Published	49 years, 3 months ago (May 1, 1976)
Published Print	49 years, 3 months ago (May 1, 1976)

Funders 0

None

BibTeX

@article{Efrima_1976, title={Outer-sphere electron-transfer reactions in polar solvents}, volume={64}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.432727}, DOI={10.1063/1.432727}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Efrima, Shlomo and Bixon, Mordechai}, year={1976}, month=may, pages={3639–3647} }

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