DOI: 10.1063/1.432599. Theoretical study of the binding of an electron to a molecular dipole: LiCl−

Theoretical study of the binding of an electron to a molecular dipole: LiCl−

10.1063/1.432599

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Ab initio calculations are carried out to determine the nature of the binding of the LiCl anion. The extra electron.is found to be in a predominantly nonbonding orbital on the lithium end of the molecule and the calculations predict an electron affinityu of LiCl of 0.54 eV. This is in good agreement with the experimental value of 0.61 eV, which has been recently determined by Carlsten, Peterson, and Lineberger. The ab initio results are discussed in light of the finite dipole model.

Bibliography

Jordan, K. D., & Luken, W. (1976). Theoretical study of the binding of an electron to a molecular dipole: LiClâ. The Journal of Chemical Physics, 64(7), 2760â2766.

Authors 2

K. D. Jordan (first)
W. Luken (additional)

References 30 Referenced 130

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{'key': '2024020913545882900_r3', 'first-page': '231', 'volume': '91', 'year': '1967', 'journal-title': 'Proc. Phys. Soc. London'} / Proc. Phys. Soc. London (1967)
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{'key': '2024020913545882900_r8a'}
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Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 5:10 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 9:41 a.m.)
Indexed	1 year, 1 month ago (July 24, 2024, 10:55 p.m.)
Issued	49 years, 4 months ago (April 1, 1976)
Published	49 years, 4 months ago (April 1, 1976)
Published Print	49 years, 4 months ago (April 1, 1976)

Funders 0

None

BibTeX

@article{Jordan_1976, title={Theoretical study of the binding of an electron to a molecular dipole: LiCl−}, volume={64}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.432599}, DOI={10.1063/1.432599}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Jordan, K. D. and Luken, W.}, year={1976}, month=apr, pages={2760–2766} }

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