Abstract
A theory for the concentration dependence of the rate of diffusion-controlled reactions is formulated. One of the reacting partners is taken to be a collection of static sinks. The steady state situation for a random distribution of these sinks is studied. The rate coefficient is predicted to increase with concentration of sinks and the dependence on concentration is shown to be nonanalytic.
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Dates
Type | When |
---|---|
Created | 22 years, 6 months ago (Feb. 27, 2003, 5:10 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 9, 2024, 10:03 a.m.) |
Indexed | 2 days, 23 hours ago (Sept. 3, 2025, 7:02 a.m.) |
Issued | 49 years, 3 months ago (June 1, 1976) |
Published | 49 years, 3 months ago (June 1, 1976) |
Published Print | 49 years, 3 months ago (June 1, 1976) |
@article{Felderhof_1976, title={Concentration dependence of the rate of diffusion-controlled reactions}, volume={64}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.432087}, DOI={10.1063/1.432087}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Felderhof, B. U. and Deutch, J. M.}, year={1976}, month=jun, pages={4551–4558} }