DOI: 10.1063/1.431483. Fluorescence and energy transfer near interfaces: The complete and quantitative description of the Eu+3/mirror systems

Fluorescence and energy transfer near interfaces: The complete and quantitative description of the Eu+3/mirror systems

10.1063/1.431483

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The classical electromagnetic description of fluorescent emission and energy transfer in the Eu+3/mirror systems is shown to be in quantitative agreement with the results of eight experimental systems studied by the fatty acid monolayer assembly technique. The emitter lifetime measured as a function of distance from the mirror(s) is found to be consistent with an isotropic spatial orientation for the emitter in all cases; furthermore, it is shown to be exclusively so in most of these cases. Both the quantum yield and the radiative lifetime of the luminescent state of the Eu+3 ion are determined by theoretical fits to the data. Whereas the quantum yield spans a range of 0.69–0.86, the radiative lifetime of the electric dipole transition at 612 nm is nearly constant, as required, with a value of 803±29 μsec. Both the quantitative agreement between theory and experiment and the consistency among the eight experimental systems in predicting the radiative lifetime provide a clear demonstration of the utility of the fatty acid monlayer assembly technique as a method of measurement of emission properties of lunimescent systems and of dielectric properties of surfaces.

Bibliography

Chance, R. R., Miller, A. H., Prock, A., & Silbey, R. (1975). Fluorescence and energy transfer near interfaces: The complete and quantitative description of the Eu+3/mirror systems. The Journal of Chemical Physics, 63(4), 1589â1595.

Authors 4

R. R. Chance (first)
A. H. Miller (additional)
A. Prock (additional)
R. Silbey (additional)

References 45 Referenced 115

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Dates

Type	When
Created	22 years, 6 months ago (Feb. 27, 2003, 3:57 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 9:08 a.m.)
Indexed	1 year, 6 months ago (Feb. 19, 2024, 2:06 p.m.)
Issued	50 years ago (Aug. 15, 1975)
Published	50 years ago (Aug. 15, 1975)
Published Print	50 years ago (Aug. 15, 1975)

Funders 0

None

BibTeX

@article{Chance_1975, title={Fluorescence and energy transfer near interfaces: The complete and quantitative description of the Eu+3/mirror systems}, volume={63}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.431483}, DOI={10.1063/1.431483}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Chance, R. R. and Miller, A. H. and Prock, A. and Silbey, R.}, year={1975}, month=aug, pages={1589–1595} }

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