Abstract
Solutions have been obtained to equations which described the interface between two immiscible polymers and are more general than the equations first introduced by Helfand and Tagami. Gaussian random−walk statistics are assumed for the macromolecules. As a consequence of the present work, limitations of the earlier theory are removed, particularly the assumption that the properties of the two polymers when pure are identical. Calculations are performed for a variety of polymers and comparison with experiment is made.
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Dates
Type | When |
---|---|
Created | 22 years, 5 months ago (Feb. 27, 2003, 4:56 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 9, 2024, 8:36 a.m.) |
Indexed | 1 month, 2 weeks ago (July 1, 2025, 12:23 a.m.) |
Issued | 50 years, 6 months ago (Feb. 15, 1975) |
Published | 50 years, 6 months ago (Feb. 15, 1975) |
Published Print | 50 years, 6 months ago (Feb. 15, 1975) |
@article{Helfand_1975, title={Theory of unsymmetric polymer–polymer interfaces}, volume={62}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.430632}, DOI={10.1063/1.430632}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Helfand, Eugene and Sapse, Anne Marie}, year={1975}, month=feb, pages={1327–1331} }