DOI: 10.1063/1.430342. Properties of intercalated 2H-NbSe2, 4Hb-TaS2, and 1T-TaS2

Properties of intercalated 2H-NbSe2, 4Hb-TaS2, and 1T-TaS2

10.1063/1.430342

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The layered compounds 2H-NbSe2, 4Hb-TaS2, and 1T-TaS2 have been intercalated with organic molecules; and the resulting crystal structure, heat capacity, conductivity, and superconductivity have been studied. The coordination in the disulfide layers was found to be unchanged in the product phase. Resistance minima appear and the superconducting transition temperature is reduced in the NbSe2 complex. Conversely, superconductivity is induced in the 4Hb-TaS2 complex. Corresponding evidence of a large change of the density of states, negative for 2H-NbSe2 and positive for 4Hb-TaS2, was also observed upon intercalation. The transport properties of all the intercalation complexes show a pronounced dependence upon the coordination of the transition metal.

Bibliography

Meyer, S. F., Howard, R. E., Stewart, G. R., Acrivos, J. V., & Geballe, T. H. (1975). Properties of intercalated 2H-NbSe2, 4Hb-TaS2, and 1T-TaS2. The Journal of Chemical Physics, 62(11), 4411â4419.

Authors 5

S. F. Meyer (first)
R. E. Howard (additional)
G. R. Stewart (additional)
J. V. Acrivos (additional)
T. H. Geballe (additional)

References 43 Referenced 114

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Dates

Type	When
Created	22 years, 5 months ago (Feb. 27, 2003, 4:56 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 8:41 a.m.)
Indexed	1 month, 2 weeks ago (July 3, 2025, 2:52 a.m.)
Issued	50 years, 2 months ago (June 1, 1975)
Published	50 years, 2 months ago (June 1, 1975)
Published Print	50 years, 2 months ago (June 1, 1975)

Funders 0

None

BibTeX

@article{Meyer_1975, title={Properties of intercalated 2H-NbSe2, 4Hb-TaS2, and 1T-TaS2}, volume={62}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.430342}, DOI={10.1063/1.430342}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Meyer, S. F. and Howard, R. E. and Stewart, G. R. and Acrivos, J. V. and Geballe, T. H.}, year={1975}, month=jun, pages={4411–4419} }

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