DOI: 10.1063/1.372593. Magnetic ordering in M(ox)(bpy) system (M=Fe, Co, Ni; ox=C2O42−; bpy=4,4′-bipyridine)

Magnetic ordering in M(ox)(bpy) system (M=Fe, Co, Ni; ox=C2O42−; bpy=4,4′-bipyridine)

10.1063/1.372593

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

The temperature and field dependence of the magnetization have been measured to investigate the magnetic properties of the first oxalate–bpy mixed-ligand framework with a general formula M(ox)(bpy) (M = Fe(II), Co(II), Ni(II); ox = C2O42−; bpy = 4,4′-bipyridine). All compounds in the M(ox)(bpy) system crystallize in an orthorhombic structure with space group Immm (No. 71), in which the magnetic M ions form one-dimensional chains along the a axis. Spontaneous magnetic orderings with transition temperatures of 12, 13, and 26 K have been found for Fe(ox)(bpy), Co(ox)(bpy), and Ni(ox)(bpy), respectively. The nature of the ordering in Ni(ox)(bpy) is antiferromagnetic, however it may exhibit a metamagnetic transition at high magnetic fields. The type of ordering in Fe(ox)(bpy) and Co(ox)(bpy) is also antiferromagnetic but with canting, or so-called weak ferromagnetism. The residual moment resulting from the canting is larger in Fe(ox)(bpy) than in Co(ox)(bpy). The values of μeff obtained by fitting χ(T) indicate a high spin state for M ions in all three compounds. The origin of the magnetic ordering in these compounds is attributed to antiferromagnetic exchange interactions between the M ions through the bridging oxalate molecules along the magnetic chain and interchain M–M couplings along the [111] direction.

Bibliography

Yuen, T., Lin, C. L., Mihalisin, T. W., Lawandy, M. A., & Li, J. (2000). Magnetic ordering in M(ox)(bpy) system (M=Fe, Co, Ni; ox=C2O42â; bpy=4,4â²-bipyridine). Journal of Applied Physics, 87(9), 6001â6003.

Authors 5

Tan Yuen (first)
C. L. Lin (additional)
T. W. Mihalisin (additional)
Michael A. Lawandy (additional)
Jing Li (additional)

References 10 Referenced 35

10.1103/PhysRevB.50.9174 / Phys. Rev. B (1994)
10.1103/PhysRevLett.77.1616 / Phys. Rev. Lett. (1996)
10.1103/PhysRevLett.79.2336 / Phys. Rev. Lett. (1997)
10.1021/ic990243w / Inorg. Chem. (1999)
10.1021/ic990286c / Inorg. Chem. (1999)
10.1143/JPSJ.30.1330 / J. Phys. Soc. Jpn. (1971)
10.1016/0038-1098(75)90815-7 / Solid State Commun. (1975)
10.1063/1.435658 / J. Chem. Phys. (1978)
10.1021/ic00191a027 / Inorg. Chem. (1984)
{'key': '2024021007580042000_r10', 'first-page': '408', 'volume': '24', 'year': '1995', 'journal-title': 'Inorg. Chem.'} / Inorg. Chem. (1995)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:43 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 4:50 a.m.)
Indexed	1 year, 3 months ago (May 28, 2024, 11:16 a.m.)
Issued	25 years, 4 months ago (May 1, 2000)
Published	25 years, 4 months ago (May 1, 2000)
Published Print	25 years, 4 months ago (May 1, 2000)

Funders 0

None

BibTeX

@article{Yuen_2000, title={Magnetic ordering in M(ox)(bpy) system (M=Fe, Co, Ni; ox=C2O42−; bpy=4,4′-bipyridine)}, volume={87}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.372593}, DOI={10.1063/1.372593}, number={9}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Yuen, Tan and Lin, C. L. and Mihalisin, T. W. and Lawandy, Michael A. and Li, Jing}, year={2000}, month=may, pages={6001–6003} }

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