DOI: 10.1063/1.371953. Structure property relations in BiFeO3/BaTiO3 solid solutions

Structure property relations in BiFeO3/BaTiO3 solid solutions

10.1063/1.371953

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

BiFeO 3 , when forming a solid solution with BaTiO3, shows structural transformations over the entire compositional range. Above 70 mole % of BiFeO3 the structure is rhombohedral and below 4 mole %, it is tetragonal. In between the structure is cubic. The ferroelectric TC decreases with increasing composition of BaTiO3 and a relatively small relaxation is observed. Impedance measurements showed a structural dependence and analysis of which has clearly shown that the capacitance observed is from the bulk of the sample. Relaxation time (τ) of BiFeO3 was estimated using the relaxation times of the intermediate compositions. Magnetization measurements showed field induced ferromagnetism. As the structure becomes cubic with increasing concentration of BaTiO3, paramagnetism sets in, as evidenced by the electron spin resonance spectra.

Bibliography

Kumar, M. M., Srinivas, A., & Suryanarayana, S. V. (2000). Structure property relations in BiFeO3/BaTiO3 solid solutions. Journal of Applied Physics, 87(2), 855â862.

Authors 3

M. Mahesh Kumar (first)
A. Srinivas (additional)
S. V. Suryanarayana (additional)

References 34 Referenced 497

10.1002/pssa.2210570108 / Phys. Status Solidi (1980)
{'key': '2024020703205873500_r2', 'first-page': '490', 'volume': '23', 'year': '1966', 'journal-title': 'Sov. Phys. JETP'} / Sov. Phys. JETP (1966)
10.1107/S0108768190006887 / Acta Crystallogr., Sect. B: Struct. Sci. (1990)
{'key': '2024020703205873500_r4', 'first-page': '18', 'volume': '12', 'year': '1960', 'journal-title': 'Sov. Phys. JETP'} / Sov. Phys. JETP (1960)
10.1016/0038-1098(70)90262-0 / Solid State Commun. (1970)
{'key': '2024020703205873500_r6', 'first-page': '816', 'volume': '8', 'year': '1966', 'journal-title': 'Fiz. Tverd. Tela (S.-Peterburg)'} / Fiz. Tverd. Tela (S.-Peterburg) (1966)
10.1063/1.1655783 / J. Appl. Phys. (1968)
{'key': '2024020703205873500_r8', 'first-page': '375', 'volume': '6', 'year': '1964', 'journal-title': 'Sov. Phys. Solid State'} / Sov. Phys. Solid State (1964)
{'key': '2024020703205873500_r9', 'first-page': '70', 'volume': '7', 'year': '1969', 'journal-title': 'Solid State Commun.'} / Solid State Commun. (1969)
{'key': '2024020703205873500_r10', 'first-page': '483', 'volume': '162', 'year': '1988', 'journal-title': 'Ferroelectrics'} / Ferroelectrics (1988)
{'key': '2024020703205873500_r11', 'first-page': '2936', 'volume': '6', 'year': '1965', 'journal-title': 'Sov. Phys. Solid State'} / Sov. Phys. Solid State (1965)
10.1063/1.342338 / J. Appl. Phys. (1988)
10.1002/pssa.2210680160 / Phys. Status Solidi A (1981)
10.1002/(SICI)1521-396X(199801)165:1<317::AID-PSSA317>3.0.CO;2-Y / Phys. Status Solidi A (1998)
10.1016/S0304-8853(98)00167-X / J. Magn. Magn. Mater. (1998)
{'key': '2024020703205873500_r16'}
{'key': '2024020703205873500_r17', 'first-page': '779', 'volume': '24', 'year': '1957', 'journal-title': 'Anglo Chem.'} / Anglo Chem. (1957)
10.1088/0022-3719/15/23/020 / J. Phys. C (1982)
10.1111/j.1151-2916.1967.tb15153.x / J. Am. Ceram. Soc. (1967)
{'key': '2024020703205873500_r19', 'first-page': '683', 'volume': '28', 'year': '1964', 'journal-title': 'Iz. ANSSSR, Ser Fiz'} / Iz. ANSSSR, Ser Fiz (1964)
10.1016/0038-1098(65)90386-8 / Solid State Commun. (1965)
{'key': '2024020703205873500_r21', 'first-page': '307', 'volume': '4', 'year': '1960', 'journal-title': 'Period. Polytech., Chem. Eng.'} / Period. Polytech., Chem. Eng. (1960)
10.1111/j.1151-2916.1996.tb08162.x / J. Am. Ceram. Soc. (1996)
10.1007/BF01132394 / J. Mater. Sci. (1987)
10.1063/1.344049 / J. Appl. Phys. (1989)
{'key': '2024020703205873500_r25', 'first-page': '601', 'volume': '29', 'year': '1994', 'journal-title': 'J. Mater. Sci.'} / J. Mater. Sci. (1994)
{'key': '2024020703205873500_r26'}
{'key': '2024020703205873500_r27', 'first-page': '755', 'volume': '44', 'year': '1982', 'journal-title': 'Ferroelectr. Lett. Sect.'} / Ferroelectr. Lett. Sect. (1982)
{'key': '2024020703205873500_r28'}
{'key': '2024020703205873500_r29'}
10.1103/PhysRevLett.75.3336 / Phys. Rev. Lett. (1995)
10.1016/S0038-1098(98)00195-1 / Solid State Commun. (1998)
{'key': '2024020703205873500_r31', 'first-page': '2074', 'volume': '8', 'year': '1967', 'journal-title': 'Sov. Phys. Solid State'} / Sov. Phys. Solid State (1967)
{'key': '2024020703205873500_r32', 'first-page': '275', 'volume': '61', 'year': '1994', 'journal-title': 'Ferroelectrics'} / Ferroelectrics (1994)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:55 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 12:48 a.m.)
Indexed	12 hours, 41 minutes ago (Aug. 28, 2025, 8:04 a.m.)
Issued	25 years, 7 months ago (Jan. 15, 2000)
Published	25 years, 7 months ago (Jan. 15, 2000)
Published Print	25 years, 7 months ago (Jan. 15, 2000)

Funders 0

None

BibTeX

@article{Kumar_2000, title={Structure property relations in BiFeO3/BaTiO3 solid solutions}, volume={87}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.371953}, DOI={10.1063/1.371953}, number={2}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Kumar, M. Mahesh and Srinivas, A. and Suryanarayana, S. V.}, year={2000}, month=jan, pages={855–862} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        28
      ]
    ],
    "date-time": "2025-08-28T12:04:54Z",
    "timestamp": 1756382694917
  },
  "reference-count": 34,
  "publisher": "AIP Publishing",
  "issue": "2",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        2000,
        1,
        15
      ]
    ]
  },
  "abstract": "<jats:p>BiFeO 3 , when forming a solid solution with BaTiO3, shows structural transformations over the entire compositional range. Above 70 mole\u200a% of BiFeO3 the structure is rhombohedral and below 4 mole\u200a%, it is tetragonal. In between the structure is cubic. The ferroelectric TC decreases with increasing composition of BaTiO3 and a relatively small relaxation is observed. Impedance measurements showed a structural dependence and analysis of which has clearly shown that the capacitance observed is from the bulk of the sample. Relaxation time (\u03c4) of BiFeO3 was estimated using the relaxation times of the intermediate compositions. Magnetization measurements showed field induced ferromagnetism. As the structure becomes cubic with increasing concentration of BaTiO3, paramagnetism sets in, as evidenced by the electron spin resonance spectra.</jats:p>",
  "DOI": "10.1063/1.371953",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        7,
        26
      ]
    ],
    "date-time": "2002-07-26T13:55:45Z",
    "timestamp": 1027691745000
  },
  "page": "855-862",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 497,
  "title": "Structure property relations in BiFeO3/BaTiO3 solid solutions",
  "prefix": "10.1063",
  "volume": "87",
  "author": [
    {
      "given": "M. Mahesh",
      "family": "Kumar",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Physics, Osmania University, Hyderabad, India-500\u2009007"
        }
      ]
    },
    {
      "given": "A.",
      "family": "Srinivas",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Physics, Osmania University, Hyderabad, India-500\u2009007"
        }
      ]
    },
    {
      "given": "S. V.",
      "family": "Suryanarayana",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Physics, Osmania University, Hyderabad, India-500\u2009007"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020703205873500_r1",
      "doi-asserted-by": "crossref",
      "first-page": "99",
      "DOI": "10.1002/pssa.2210570108",
      "volume": "57",
      "year": "1980",
      "journal-title": "Phys. Status Solidi"
    },
    {
      "key": "2024020703205873500_r2",
      "first-page": "490",
      "volume": "23",
      "year": "1966",
      "journal-title": "Sov. Phys. JETP"
    },
    {
      "key": "2024020703205873500_r3",
      "doi-asserted-by": "crossref",
      "first-page": "698",
      "DOI": "10.1107/S0108768190006887",
      "volume": "46",
      "year": "1990",
      "journal-title": "Acta Crystallogr., Sect. B: Struct. Sci."
    },
    {
      "key": "2024020703205873500_r4",
      "first-page": "18",
      "volume": "12",
      "year": "1960",
      "journal-title": "Sov. Phys. JETP"
    },
    {
      "key": "2024020703205873500_r5",
      "doi-asserted-by": "crossref",
      "first-page": "1073",
      "DOI": "10.1016/0038-1098(70)90262-0",
      "volume": "8",
      "year": "1970",
      "journal-title": "Solid State Commun."
    },
    {
      "key": "2024020703205873500_r6",
      "first-page": "816",
      "volume": "8",
      "year": "1966",
      "journal-title": "Fiz. Tverd. Tela (S.-Peterburg)"
    },
    {
      "key": "2024020703205873500_r7",
      "doi-asserted-by": "crossref",
      "first-page": "70",
      "DOI": "10.1063/1.1655783",
      "volume": "39",
      "year": "1968",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024020703205873500_r8",
      "first-page": "375",
      "volume": "6",
      "year": "1964",
      "journal-title": "Sov. Phys. Solid State"
    },
    {
      "key": "2024020703205873500_r9",
      "first-page": "70",
      "volume": "7",
      "year": "1969",
      "journal-title": "Solid State Commun."
    },
    {
      "key": "2024020703205873500_r10",
      "first-page": "483",
      "volume": "162",
      "year": "1988",
      "journal-title": "Ferroelectrics"
    },
    {
      "key": "2024020703205873500_r11",
      "first-page": "2936",
      "volume": "6",
      "year": "1965",
      "journal-title": "Sov. Phys. Solid State"
    },
    {
      "key": "2024020703205873500_r12",
      "doi-asserted-by": "crossref",
      "first-page": "5434",
      "DOI": "10.1063/1.342338",
      "volume": "64",
      "year": "1988",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024020703205873500_r13",
      "doi-asserted-by": "crossref",
      "first-page": "K81",
      "DOI": "10.1002/pssa.2210680160",
      "volume": "68",
      "year": "1981",
      "journal-title": "Phys. Status Solidi A"
    },
    {
      "key": "2024020703205873500_r14",
      "doi-asserted-by": "crossref",
      "first-page": "317",
      "DOI": "10.1002/(SICI)1521-396X(199801)165:1<317::AID-PSSA317>3.0.CO;2-Y",
      "volume": "165",
      "year": "1998",
      "journal-title": "Phys. Status Solidi A"
    },
    {
      "key": "2024020703205873500_r15",
      "doi-asserted-by": "crossref",
      "first-page": "203",
      "DOI": "10.1016/S0304-8853(98)00167-X",
      "volume": "188",
      "year": "1998",
      "journal-title": "J. Magn. Magn. Mater."
    },
    {
      "key": "2024020703205873500_r16"
    },
    {
      "key": "2024020703205873500_r17",
      "first-page": "779",
      "volume": "24",
      "year": "1957",
      "journal-title": "Anglo Chem."
    },
    {
      "key": "2024020703205873500_r18",
      "doi-asserted-by": "crossref",
      "first-page": "4835",
      "DOI": "10.1088/0022-3719/15/23/020",
      "volume": "15",
      "year": "1982",
      "journal-title": "J. Phys. C"
    },
    {
      "key": "2024020703205873500_r18a",
      "doi-asserted-by": "crossref",
      "first-page": "437",
      "DOI": "10.1111/j.1151-2916.1967.tb15153.x",
      "volume": "50",
      "year": "1967",
      "journal-title": "J. Am. Ceram. Soc."
    },
    {
      "key": "2024020703205873500_r19",
      "first-page": "683",
      "volume": "28",
      "year": "1964",
      "journal-title": "Iz. ANSSSR, Ser Fiz"
    },
    {
      "key": "2024020703205873500_r20",
      "doi-asserted-by": "crossref",
      "first-page": "123",
      "DOI": "10.1016/0038-1098(65)90386-8",
      "volume": "3",
      "year": "1965",
      "journal-title": "Solid State Commun."
    },
    {
      "key": "2024020703205873500_r21",
      "first-page": "307",
      "volume": "4",
      "year": "1960",
      "journal-title": "Period. Polytech., Chem. Eng."
    },
    {
      "key": "2024020703205873500_r22",
      "doi-asserted-by": "crossref",
      "first-page": "536",
      "DOI": "10.1111/j.1151-2916.1996.tb08162.x",
      "volume": "79",
      "year": "1996",
      "journal-title": "J. Am. Ceram. Soc."
    },
    {
      "key": "2024020703205873500_r23",
      "doi-asserted-by": "crossref",
      "first-page": "1694",
      "DOI": "10.1007/BF01132394",
      "volume": "22",
      "year": "1987",
      "journal-title": "J. Mater. Sci."
    },
    {
      "key": "2024020703205873500_r24",
      "doi-asserted-by": "crossref",
      "first-page": "3850",
      "DOI": "10.1063/1.344049",
      "volume": "66",
      "year": "1989",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024020703205873500_r25",
      "first-page": "601",
      "volume": "29",
      "year": "1994",
      "journal-title": "J. Mater. Sci."
    },
    {
      "key": "2024020703205873500_r26"
    },
    {
      "key": "2024020703205873500_r27",
      "first-page": "755",
      "volume": "44",
      "year": "1982",
      "journal-title": "Ferroelectr. Lett. Sect."
    },
    {
      "key": "2024020703205873500_r28"
    },
    {
      "key": "2024020703205873500_r29"
    },
    {
      "key": "2024020703205873500_r30",
      "doi-asserted-by": "crossref",
      "first-page": "3336",
      "DOI": "10.1103/PhysRevLett.75.3336",
      "volume": "75",
      "year": "1995",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020703205873500_r30a",
      "doi-asserted-by": "crossref",
      "first-page": "363",
      "DOI": "10.1016/S0038-1098(98)00195-1",
      "volume": "107",
      "year": "1998",
      "journal-title": "Solid State Commun."
    },
    {
      "key": "2024020703205873500_r31",
      "first-page": "2074",
      "volume": "8",
      "year": "1967",
      "journal-title": "Sov. Phys. Solid State"
    },
    {
      "key": "2024020703205873500_r32",
      "first-page": "275",
      "volume": "61",
      "year": "1994",
      "journal-title": "Ferroelectrics"
    }
  ],
  "container-title": "Journal of Applied Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jap/article-pdf/87/2/855/19275159/855_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jap/article-pdf/87/2/855/19275159/855_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        7
      ]
    ],
    "date-time": "2024-02-07T05:48:38Z",
    "timestamp": 1707284918000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jap/article/87/2/855/178497/Structure-property-relations-in-BiFeO3-BaTiO3"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2000,
        1,
        15
      ]
    ]
  },
  "references-count": 34,
  "journal-issue": {
    "issue": "2",
    "published-print": {
      "date-parts": [
        [
          2000,
          1,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.371953",
  "relation": {},
  "ISSN": [
    "0021-8979",
    "1089-7550"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        2000,
        1,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        2000,
        1,
        15
      ]
    ]
  }
}