DOI: 10.1063/1.369027. Raman spectroscopic studies on well-defined carbonaceous materials of strong two-dimensional character

Raman spectroscopic studies on well-defined carbonaceous materials of strong two-dimensional character

10.1063/1.369027

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

Using 514 nm radiation and a careful experimental protocol allowing us to make quantitative intensity analyses, we have examined the first- and second-order Raman spectra of five varieties of graphite. These include single-crystal graphite and highly oriented pyrolytic graphite as references, then two with a significant content of c-axis translation faults introduced through grinding and exfoliation, and a last sample which is purely turbostratic. We show that full c-axis stacking disorder results in a strong increase of the scattered E2g-mode intensity. We have further shown that even in those strongly disordered stacking sequences, but in which the AB sequence persists over only a few layers, the doublet around 2700 cm−1 is resolved. We argue against assigning the peak around 1355 cm−1 to “disorder,” as is so often done, but to the finite in-plane domain size as proposed a number of years ago; moreover, we suggest that this peak is a more sensitive probe of such small domains than is x-ray diffraction.

Bibliography

Wilhelm, H., Lelaurain, M., McRae, E., & Humbert, B. (1998). Raman spectroscopic studies on well-defined carbonaceous materials of strong two-dimensional character. Journal of Applied Physics, 84(12), 6552â6558.

Authors 4

H. Wilhelm (first)
M. Lelaurain (additional)
E. McRae (additional)
B. Humbert (additional)

References 41 Referenced 173

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:33 a.m.)
Deposited	2 years, 1 month ago (July 11, 2023, 1:37 a.m.)
Indexed	2 months, 1 week ago (June 24, 2025, 7:43 a.m.)
Issued	26 years, 8 months ago (Dec. 15, 1998)
Published	26 years, 8 months ago (Dec. 15, 1998)
Published Print	26 years, 8 months ago (Dec. 15, 1998)

Funders 0

None

BibTeX

@article{Wilhelm_1998, title={Raman spectroscopic studies on well-defined carbonaceous materials of strong two-dimensional character}, volume={84}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.369027}, DOI={10.1063/1.369027}, number={12}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Wilhelm, H. and Lelaurain, M. and McRae, E. and Humbert, B.}, year={1998}, month=dec, pages={6552–6558} }

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