Crossref journal-article
AIP Publishing
Journal of Applied Physics (317)
Abstract

The use of a new highly luminescent conjugated polymer as an emissive layer in single and multilayer electroluminescence devices is reported. Poly(m-phenylenevinylene-co-2,5 -dioctyloxy-p-phenylenevinylene) [PmPV-co-DOctOPV] was prepared via a Wittig synthesis reaction. The resulting polymer has a high photoluminescence quantum efficiency in the solid state with an emission spectrum peaked at 506 nm (2.45 eV) in the green. Electroluminescence devices were fabricated with an ITO anode and a MgAg cathode. Three different structures were studied: (i) single layer devices containing only PmPV-co-DOctOPV; (ii) double layer devices with PmPV-co-DOctOPV and an evaporated film of 1,3-bis(4-tert-butylphenyl-1,3,4-oxadiazoyl) phenylene [OXD-7] as an electron transport layer; (iii) triple layer devices containing PmPV-co-DOctOPV, OXD-7 and in addition a polyvinylcarbazole hole transport layer. Electroluminescence external quantum efficiencies for these devices were found to be up to 0.08%, 0.55%, and 1%, respectively, corresponding to luminous efficiencies of ≈0.5, ≈3, and ≈6 lm/W and power efficiencies of 8.5×10−5, 5.9×10−4, and 6.0×10−4 W/W.

Bibliography

O’Brien, D., Bleyer, A., Lidzey, D. G., Bradley, D. D. C., & Tsutsui, T. (1997). Efficient multilayer electroluminescence devices with poly(m-phenylenevinylene-co-2,5-dioctyloxy-p-phenylenevinylene) as the emissive layer. Journal of Applied Physics, 82(5), 2662–2670.

Authors 5
  1. D. O’Brien (first)
  2. A. Bleyer (additional)
  3. D. G. Lidzey (additional)
  4. D. D. C. Bradley (additional)
  5. T. Tsutsui (additional)
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Dates
Type When
Created 23 years, 1 month ago (July 26, 2002, 9:33 a.m.)
Deposited 1 year, 7 months ago (Feb. 2, 2024, 3:38 p.m.)
Indexed 1 year, 3 months ago (May 30, 2024, 12:34 a.m.)
Issued 28 years ago (Sept. 1, 1997)
Published 28 years ago (Sept. 1, 1997)
Published Print 28 years ago (Sept. 1, 1997)
Funders 0

None

@article{O_Brien_1997, title={Efficient multilayer electroluminescence devices with poly(m-phenylenevinylene-co-2,5-dioctyloxy-p-phenylenevinylene) as the emissive layer}, volume={82}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.366097}, DOI={10.1063/1.366097}, number={5}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={O’Brien, D. and Bleyer, A. and Lidzey, D. G. and Bradley, D. D. C. and Tsutsui, T.}, year={1997}, month=sep, pages={2662–2670} }