DOI: 10.1063/1.3603965. Polarized Raman spectroscopic study on the solvent state of glassy LiCl aqueous solutions and the state of relaxed high-density amorphous ices

Polarized Raman spectroscopic study on the solvent state of glassy LiCl aqueous solutions and the state of relaxed high-density amorphous ices

10.1063/1.3603965

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We measure polarized OH-stretching Raman spectra of the glassy lithium chloride aqueous solutions (LiClaq solutions) and the relaxed high-density amorphous ices (HDA). The totally OH symmetric vibrational mode around 3100 cm−1 (g1 mode) for the glassy LiClaq solutions of 14.3 mol% and the g1 mode for the glassy LiClaq solution of 10.0 mol% seem to be similar to the g1 mode for HDA at high pressure and the g1 mode for HDA at 1 atm, respectively. This indicates that the solvent state of glassy LiClaq solution relates to the state of HDA and that the attenuation of the salt effect on water is equivalent to the attenuation of the pressure effect on water. This suggests a possibility that the hydration in electrolyte aqueous solution may relate to high-density liquid water.

Bibliography

Suzuki, Y., & Tominaga, Y. (2011). Polarized Raman spectroscopic study on the solvent state of glassy LiCl aqueous solutions and the state of relaxed high-density amorphous ices. The Journal of Chemical Physics, 134(24).

Authors 2

Yoshiharu Suzuki (first)
Yasunori Tominaga (additional)

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Dates

Type	When
Created	14 years, 1 month ago (June 30, 2011, 12:27 p.m.)
Deposited	2 years ago (Aug. 5, 2023, 2:34 a.m.)
Indexed	3 weeks, 1 day ago (July 30, 2025, 6:56 a.m.)
Issued	14 years, 1 month ago (June 28, 2011)
Published	14 years, 1 month ago (June 28, 2011)
Published Online	14 years, 1 month ago (June 29, 2011)
Published Print	14 years, 1 month ago (June 28, 2011)

Funders 0

None

BibTeX

@article{Suzuki_2011, title={Polarized Raman spectroscopic study on the solvent state of glassy LiCl aqueous solutions and the state of relaxed high-density amorphous ices}, volume={134}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.3603965}, DOI={10.1063/1.3603965}, number={24}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Suzuki, Yoshiharu and Tominaga, Yasunori}, year={2011}, month=jun }

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  },
  "article-number": "244511"
}