DOI: 10.1063/1.3597606. Increased fraction of low-density structures in aqueous solutions of fluoride

Increased fraction of low-density structures in aqueous solutions of fluoride

10.1063/1.3597606

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

X-ray absorption spectroscopy (XAS) and small angle x-ray scattering (SAXS) were utilized to study the effect of fluoride (F−) anion in aqueous solutions. XAS spectra show that F− increases the number of strong H-bonds, likely between F− and water in the first hydration shell. SAXS data show a low-Q scattering intensity increase similar to the effect of a temperature decrease, suggesting an enhanced anomalous scattering behavior in F− solutions. Quantitative analysis revealed that fluoride solutions have larger correlation lengths than chloride solutions with the same cations but shorter compared to pure water. This is interpreted as an increased fraction of tetrahedral low-density structures in the solutions due to the presence of the F− ions, which act as nucleation centers replacing water in the H-bonding network and forming stronger H-bonds, but the presence of the cations restricts the extension of strong H-bonds.

Bibliography

Waluyo, I., Huang, C., Nordlund, D., Weiss, T. M., Pettersson, L. G. M., & Nilsson, A. (2011). Increased fraction of low-density structures in aqueous solutions of fluoride. The Journal of Chemical Physics, 134(22).

Authors 6

Iradwikanari Waluyo (first)
Congcong Huang (additional)
Dennis Nordlund (additional)
Thomas M. Weiss (additional)
Lars G. M. Pettersson (additional)
Anders Nilsson (additional)

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Dates

Type	When
Created	14 years, 2 months ago (June 15, 2011, 9:11 a.m.)
Deposited	2 years, 2 months ago (June 26, 2023, 1:10 a.m.)
Indexed	2 weeks ago (Aug. 20, 2025, 8:40 a.m.)
Issued	14 years, 2 months ago (June 14, 2011)
Published	14 years, 2 months ago (June 14, 2011)
Published Online	14 years, 2 months ago (June 14, 2011)
Published Print	14 years, 2 months ago (June 14, 2011)

Funders 1

National Science Foundation 10.13039/100000001
Region: Americas
gov (National government)
Labels4
1. U.S. National Science Foundation
2. NSF
3. US NSF
4. USA NSF
Awards1
1. CHE-0809324

BibTeX

@article{Waluyo_2011, title={Increased fraction of low-density structures in aqueous solutions of fluoride}, volume={134}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.3597606}, DOI={10.1063/1.3597606}, number={22}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Waluyo, Iradwikanari and Huang, Congcong and Nordlund, Dennis and Weiss, Thomas M. and Pettersson, Lars G. M. and Nilsson, Anders}, year={2011}, month=jun }

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  "abstract": "<jats:p>X-ray absorption spectroscopy (XAS) and small angle x-ray scattering (SAXS) were utilized to study the effect of fluoride (F\u2212) anion in aqueous solutions. XAS spectra show that F\u2212 increases the number of strong H-bonds, likely between F\u2212 and water in the first hydration shell. SAXS data show a low-Q scattering intensity increase similar to the effect of a temperature decrease, suggesting an enhanced anomalous scattering behavior in F\u2212 solutions. Quantitative analysis revealed that fluoride solutions have larger correlation lengths than chloride solutions with the same cations but shorter compared to pure water. This is interpreted as an increased fraction of tetrahedral low-density structures in the solutions due to the presence of the F\u2212 ions, which act as nucleation centers replacing water in the H-bonding network and forming stronger H-bonds, but the presence of the cations restricts the extension of strong H-bonds.</jats:p>",
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